N-hydroxyphthalimide-initiated radical polymerization of vinyl monomers

被引：5

作者：

Opeida, I. A. ^{[1
]}

Kompanets, M. A. ^{[1
]}

Kushch, O. V. ^{[1
]}

Matvienko, A. G. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Litvinenko Inst Physicoorgan Chem & Coal Chem, Donetsk, Ukraine

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2007年 / 80卷 / 10期

关键词：

Radical Polymerization; Methyl Methacrylate; AIBN; Acrylonitrile; Benzoyl Peroxide;

D O I：

10.1134/S1070427207100230

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The initiating ability of N-hydroxyphthalimide in polymerization of methyl methacrylate and acrylonitrile was examined. For the polymerization of methyl methacrylate, the initial polymerization rates and activation energies were determined, and the dependences of the polymerization rates on the initiator and monomer concentrations were evaluated. An initiation mechanism was suggested.

引用

页码：1717 / 1720

页数：4

共 9 条

[1] Synthesis of aromatic aldehydes by aerobic oxidation of hydroaromatic compounds and diarylalkanes using N-hydroxyphthalimide (NHPI) as a key catalyst [J].

Aoki, Y ;

Sakaguchi, S ;

Ishii, Y .

TETRAHEDRON, 2006, 62 (11) :2497-2500

[2]

BAGDASAR KS, 1966, RADICAL POLYM THEORY

[3]

Brandrup J., 1999, POLYM HDB, P2250, DOI 10.1002/1097-0126(200007)49

[4]

Gordon A. J., 1972, CHEMISTS COMPANION H

[5] A NOVEL CATALYSIS OF N-HYDROXYPHTHALIMIDE IN THE OXIDATION OF ORGANIC SUBSTRATES BY MOLECULAR-OXYGEN [J].

ISHII, Y ;

NAKAYAMA, K ;

TAKENO, M ;

SAKAGUCHI, S ;

IWAHAMA, T ;

NISHIYAMA, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (13) :3934-3935

[6]

KONDRATEV VN, 1974, ENERGY CLEAVAGE CHEM

[7]

MOGILEVICH MM, 1990, OXIDATION OXIDATION

[8]

SATO T, 1979, MAKROMOL CHEM, V180, P1175

[9] Organocatalytic oxidations mediated by nitroxyl radicals [J].

Sheldon, RA ;

Arends, IWCE .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (9-10) :1051-1071

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