High-rate synthesis of graphene by a lower cost chemical vapor deposition route

被引:10
作者
Dayou, Sebastian [1 ]
Vigolo, Brigitte [2 ]
Desforges, Alexandre [2 ]
Ghanbaja, Jaafar [2 ]
Mohamed, Abdul Rahman [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Perai, Pulau Pinang, Malaysia
[2] Univ Lorraine, CNRS, Inst Jean Lamour, BP 70239, F-54506 Vandouvre Les Nancy, France
关键词
Graphene; Chemical vapor deposition; Synthesis rate; Metal particles; Catalyst; Thermogravimetric analysis; High yield production; SINGLE-CRYSTAL GRAPHENE; WALLED CARBON NANOTUBES; GROWTH; CHALLENGES; NANOSHEETS; SUBSTRATE; OXIDATION; CATALYST; DEVICES; STORAGE;
D O I
10.1007/s11051-017-4034-0
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemical vapor deposition (CVD) reaction from metal particles to produce graphene has seldom been reported so far. In this paper, the CVD growth of graphene was conducted under ambient pressure without a dedicated stage for reduction treatment. Interestingly, copper nanoparticles supported on MgO prepared by simple impregnation were able to efficiently catalyze graphene. Quantification of the prepared graphene was carefully conducted. For the optimized conditions, 1000 degrees C for 30 min, high content of graphene (up to 27 at.%) could be produced. Our method shows high efficiency and growth rate of graphene, produced at much lower cost compared to the existing methods.
引用
收藏
页数:9
相关论文
共 44 条
[1]   Epitaxial Chemical Vapor Deposition Growth of Single-Layer Graphene over Cobalt Film Crystallized on Sapphire [J].
Ago, Hiroki ;
Ito, Yoshito ;
Mizuta, Noriaki ;
Yoshida, Kazuma ;
Hu, Baoshan ;
Orofeo, Carlo M. ;
Tsuji, Masaharu ;
Ikeda, Ken-ichi ;
Mizuno, Seigi .
ACS NANO, 2010, 4 (12) :7407-7414
[2]  
Aksel C., 2006, Ceramic Matrix Composites. Microstructure, Properties and Applications, P359, DOI 10.1533/9781845691066.4.359
[3]   Graphene synthesis on Fe foil using thermal CVD [J].
An, Hyosub ;
Lee, Won-Jun ;
Jung, Jongwan .
CURRENT APPLIED PHYSICS, 2011, 11 (04) :S81-S85
[4]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[5]   Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst [J].
Bhaviripudi, Sreekar ;
Jia, Xiaoting ;
Dresselhaus, Mildred S. ;
Kong, Jing .
NANO LETTERS, 2010, 10 (10) :4128-4133
[6]  
Bonaccorso F, 2010, NAT PHOTONICS, V4, P611, DOI [10.1038/NPHOTON.2010.186, 10.1038/nphoton.2010.186]
[7]   Carbon nanotubes and graphene towards soft electronics [J].
Chae S.H. ;
Lee Y.H. .
Nano Convergence, 1 (1)
[8]   Synthesis of Large-Area Graphene Layers on Poly-Nickel Substrate by Chemical Vapor Deposition: Wrinkle Formation [J].
Chae, Seung Jin ;
Guenes, Fethullah ;
Kim, Ki Kang ;
Kim, Eun Sung ;
Han, Gang Hee ;
Kim, Soo Min ;
Shin, Hyeon-Jin ;
Yoon, Seon-Mi ;
Choi, Jae-Young ;
Park, Min Ho ;
Yang, Cheol Woong ;
Pribat, Didier ;
Lee, Young Hee .
ADVANCED MATERIALS, 2009, 21 (22) :2328-+
[9]   Bulk growth of mono- to few-layer graphene on nickel particles by chemical vapor deposition from methane [J].
Chen, Zongping ;
Ren, Wencai ;
Liu, Bilu ;
Gao, Libo ;
Pei, Songfeng ;
Wu, Zhong-Shuai ;
Zhao, Jinping ;
Cheng, Hui-Ming .
CARBON, 2010, 48 (12) :3543-3550
[10]   Direct Chemical Vapor Deposition Growth of Graphene Nanosheets on Supported Copper Oxide [J].
Dayou, Sebastian ;
Vigolo, Brigitte ;
Ghanbaja, Jaafar ;
Medjahdi, Ghouti ;
Thirmizir, Mohd Zharif Ahmad ;
Pauzi, Hariy ;
Mohamed, Abdul Rahman .
CATALYSIS LETTERS, 2017, 147 (08) :1988-1997