High-performance natural rubber latex composites developed by a green approach using ionic liquid-modified multiwalled carbon nanotubes

被引：22
作者：
Ge, Yi [1 ]
Zhang, Qianyun [1 ]
Zhang, Yandan [1 ]
Liu, Fusheng [1 ]
Han, Jingjie [1 ]
Wu, Chifei [2 ]
机构：
[1] Qingdao Univ Sci & Technol, Sch Chem Engn, Qingdao 266042, Peoples R China
[2] East China Univ Sci & Technol, Shanghai 200237, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2018年 / 135卷 / 38期
关键词：
functionalization of polymers; graphene and fullerenes; ionic liquids; nanotubes; rubber; MECHANICAL-PROPERTIES; NANOCOMPOSITES; DISPERSION; FUNCTIONALIZATION; POLYMERIZATION; NANOPARTICLES;
D O I：
10.1002/app.46588
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The effect of multiwalled carbon nanotubes (MWCNTs) modified by a hydrophilic ionic liquids (ILs), including 1-ethyl-3-methylimidazolium bromide and 1-hexyl-3-methylimidazolium bromide, was studied. The obtained water-suspensible carbon nanotubes (CNTs) were still homogeneously distributed in water a month after sonication. The microstructural development of filler networks and the uniform dispersion of MWCNTs in the presence of IL were analyzed by TEM. The apparent physical (cation-/-) interaction between the MWCNTs and the IL was characterized by Raman spectroscopy, DSC, and TGA. Furthermore, high-performance composites of natural rubber latex (NRL) and CNTs modified with IL were obtained by the liquid latex blending method. The CNTs were homogeneously distributed in the matrix and CNT-ILs improved the fatigue resistance and mechanical properties of the NRL/CNT-IL composites. This study demonstrates a simple and eco-friendly approach to develop multifunctional advanced materials based on IL-modified MWCNT elastomer composites. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46588.
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页数：7
相关论文
共 25 条
[1]   Transport characteristics of organic solvents through carbon nanotube filled styrene butadiene rubber nanocomposites: the influence of rubber-filler interaction, the degree of reinforcement and morphology [J].
Abraham, Jiji ;
Maria, Hanna J. ;
George, Soney C. ;
Kalarikkal, Nandakumar ;
Thomas, Sabu .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (17) :11217-11228
[2]   SWNT-filled thermoplastic and elastomeric composites prepared by miniemulsion polymerization [J].
Barraza, HJ ;
Pompeo, F ;
O'Rear, EA ;
Resasco, DE .
NANO LETTERS, 2002, 2 (08) :797-802
[3]  
Dubois P, 2006, ADV ENG MATER, V8, P147, DOI 10.1002/adem.200500256
[4]   Mechanical properties of carbon nanoparticle-reinforced elastomers [J].
Frogley, MD ;
Ravich, D ;
Wagner, HD .
COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (11) :1647-1654
[5]   Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes [J].
Fukushima, T ;
Kosaka, A ;
Ishimura, Y ;
Yamamoto, T ;
Takigawa, T ;
Ishii, N ;
Aida, T .
SCIENCE, 2003, 300 (5628) :2072-2074
[6]   Preparation of Water-suspensible Carbon Nanoparticles and Their Influence on the Properties of Epoxidized Natural Rubber Latex [J].
Han, Jingjie ;
Ge, Yi ;
Zhang, Yandan ;
Liu, Fusheng ;
Ma, Yulu .
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2017, 56 (06) :409-419
[7]   Effect of reynolds number on the dispersion of carbon black in natural rubber latex and filler-rubber interfacial interaction in high-speed jet flow field [J].
Han, Jingjie ;
Zhang, Yandan ;
Wu, Chifei ;
Ma, Yulu .
POLYMER COMPOSITES, 2013, 34 (07) :1071-1075
[8]   In-situ polymerization of olefins on nanoparticles or fibers by metallocene catalysts [J].
Kaminsky, W. ;
Funck, A. ;
Klinke, C. .
TOPICS IN CATALYSIS, 2008, 48 (1-4) :84-90
[9]   Interaction of 1-allyl-3-methyl-imidazolium chloride and carbon black and its influence on carbon black filled rubbers [J].
Kreyenschulte, Hermann ;
Richter, Sven ;
Goetze, Thomas ;
Fischer, Dieter ;
Steinhauser, Dagmar ;
Klueppel, Manfred ;
Heinrich, Gert .
CARBON, 2012, 50 (10) :3649-3658
[10]   Thermal and mechanical properties of single-walled carbon nanotube bundle-reinforced epoxy nanocomposites: the role of solvent for nanotube dispersion [J].
Lau, KT ;
Lu, M ;
Lam, CK ;
Cheung, HY ;
Sheng, FL ;
Li, HL .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (05) :719-725
123