Growth history and textures of quartz twinned in accordance with the Japan law

被引:2
作者
Momma, Koichi [1 ]
Nagase, Toshiro [2 ]
Kuribayashi, Takahiro [1 ]
Kudoh, Yasuhiro [1 ]
机构
[1] Tohoku Univ, Dept Earth & Planetary Mat Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan
[2] Tohoku Univ Museum, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
quartz; Japan twin; Brazil twin; cathodoluminescence; molecular dynamics; crystal growth; twinning; X-RAY; BOUNDARIES; CRYSTALS; DYNAMICS; SIMULATIONS;
D O I
10.1127/ejm/2014/0026-2411
中图分类号
P57 [矿物学];
学科分类号
070901 ;
摘要
The growth history of quartz twinned according to the Japan law and the development of fine textures near Japan twin boundaries were analysed using optical microscopy, cathodoluminescence, and computational simulations. Cathodoluminescence images of the samples show two distinct growth stages. In the early growth stage, growth sectors of rhombohedral faces bordered by the {11 (2) over bar2} composition plane serve as preferential growth sites that grow approximately 1.5-1.8 times faster than the other symmetrically equivalent faces. Thus, the samples initially exhibit a "fan-shape". The composition plane is quite straight and parallel to {11 (2) over bar2} in the growth sectors of rhombohedral faces but undulates in the growth sectors of prism faces. In the later growth stage, the twinned crystals grow rather isotropically and change into "V-shape". Prism faces start to develop at the composition plane, which is no longer parallel to {11 (2) over bar2}. Observations of etched figures show that fine Brazil twin lamellae are concentrated almost exclusively near the Japan twin boundary. In the early growth stage, polysynthetic Brazil twin lamellae are formed in an hourglass-shaped sector, and the lamellae develop progressively as the Japan twin grows. However, there are considerably fewer lamellae in the later growth stage. Structures at the intersection of Japan and Brazil twin boundaries were modelled using molecular dynamics simulations. The intersections of Brazil and Japan twin boundaries were found to be structurally coherent when they have certain composition planes. The results imply that Japan twin boundaries only have structural diversity, allowing either right-handed or left-handed quartz to grow coherently on the substrate crystals, when the composition plane of Japan twin is parallel to {11 (2) over bar2} and rhombohedral faces are bordered by the {11 (2) over bar2} composition plane. This structural diversity of the {11 (2) over bar2} Japan twin boundaries causes development of fine Brazil twin lamellae and triggers faster growth rate of rhombohedral faces bordered by the straight {11 (2) over bar2} composition plane.
引用
收藏
页码:71 / 80
页数:10
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