Effect of magnesia on the degradability and bioactivity of sol-gel derived SiO2-CaO-MgO-P2O5 system glasses

被引:85
作者
Ma, J. [1 ,2 ]
Chen, C. Z. [1 ,2 ]
Wang, D. G. [1 ,2 ]
Jiao, Y. [1 ,2 ]
Shi, J. Z. [1 ,2 ]
机构
[1] Shandong Univ, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Shandong, Peoples R China
[2] Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Shandong, Peoples R China
基金
美国国家科学基金会;
关键词
Bioactive glass; Magnesia; Degradation; Bioactivity; Sol-gel; IN-VITRO BIOACTIVITY; COMPOSITIONAL DEPENDENCE; APATITE LAYER; BONE; CERAMICS; INVITRO; SURFACE; HYDROXYAPATITE; CRYSTALLINITY; CAO-SIO2-P2O5;
D O I
10.1016/j.colsurfb.2010.06.022
中图分类号
Q6 [生物物理学];
学科分类号
071011 ;
摘要
Mesoporous 58SiO(2)-(38 - x)CaO-xMgO-4P(2)O(5) glasses (where x = 0, 5, 10 and 20 mol%) have been prepared by the sol-gel synthesis route. The effects of the substitution of MgO for CaO on glass degradation and bioactivity were studied in tris-(hydroxymethyl)-aminomethane and hydrochloric acid buffer solution (Tris-HCl) and simulated body fluid (SBF), respectively. Iris observed that the synthesized glasses with various MgO contents possess the similar textural properties. The studies of in vitro degradability and bioactivity show that the rate of glass degradation gradually decreases with the increase of MgO and the formation of apatite layer on glass surface is retarded. The influences of the composition upon glass properties are explained in terms of their internal structures. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:87 / 95
页数:9
相关论文
共 59 条
[1]   ON THE BIOACTIVITY OF SILICATE GLASS [J].
ANDERSSON, OH ;
KARLSSON, KH .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 129 (1-3) :145-151
[2]   Physicochemical properties of calcium phosphate coatings produced by pulsed laser deposition at different water vapour pressures [J].
Arias, JL ;
García-Sanz, FJ ;
Mayor, MB ;
Chiussi, S ;
Pou, J ;
León, B ;
Pérez-Amor, M .
BIOMATERIALS, 1998, 19 (10) :883-888
[3]   Sol gel derived SiO2-CaO-MgO-P2O5 bioglass system-preparation and in vitro characterization [J].
Balamurugan, A. ;
Ballossier, G. ;
Michel, J. ;
Kannan, S. ;
Benhayoune, H. ;
Rebelo, A. H. S. ;
Ferreira, J. M. F. .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2007, 83B (02) :546-553
[4]   Synthesis and characterisation of sol gel derived bioactive glass for biomedical applications [J].
Balamurugan, A. ;
Sockalingum, G. ;
Michel, J. ;
Faure, J. ;
Banchet, V. ;
Wortham, L. ;
Bouthors, S. ;
Laurent-Maquin, D. ;
Balossier, G. .
MATERIALS LETTERS, 2006, 60 (29-30) :3752-3757
[5]   Effect of the substitution of M2O3 (M = La, Y, In, Ga, Al) for CaO on the bioactivity of 2.5CaO•2SiO2 glass [J].
Branda, F ;
Arcobello-Varlese, F ;
Costantini, A ;
Luciani, G .
BIOMATERIALS, 2002, 23 (03) :711-716
[6]   Improvement of bioactivity with magnesium and fluorine ions incorporated hydroxyapatite coatings via sol-gel deposition on Ti6Al4V alloys [J].
Cai, Yanli ;
Zhang, Sam ;
Zeng, Xianting ;
Wang, Yongsheng ;
Qjan, Min ;
Weng, Wenjian .
THIN SOLID FILMS, 2009, 517 (17) :5347-5351
[7]   In vitro degradation studies of calcium phosphate glass ceramics prepared by controlled crystallization [J].
Dias, AG ;
Lopes, MA ;
Gibson, IR ;
Santos, JD .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 330 (1-3) :81-89
[8]   In vitro bioactivity of melt-derived glass 46S6 doped with magnesium [J].
Dietrich, Elodie ;
Oudadesse, Hassane ;
Lucas-Girot, Anita ;
Mami, Mohamed .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2009, 88A (04) :1087-1096
[9]   BIOACTIVITY OF FE2O3-CONTAINING CAO-SIO2 GLASSES - IN-VITRO EVALUATION [J].
EBISAWA, Y ;
KOKUBO, T ;
OHURA, K ;
YAMAMURO, T .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1993, 4 (03) :225-232
[10]   BIOACTIVITY OF CAO.SIO2-BASED GLASSES - INVITRO EVALUATION [J].
EBISAWA, Y ;
KOKUBO, T ;
OHURA, K ;
YAMAMURO, T .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1990, 1 (04) :239-244