An Ex-ante LCA Study of Rare Earth Extraction from NdFeB Magnet Scrap Using Molten Salt Electrolysis

被引:26
作者
Schulze, Rita [1 ,2 ,3 ]
Abbasalizadeh, Aida [4 ]
Bulach, Winfried [1 ]
Schebek, Liselotte [2 ]
Buchert, Matthias [1 ]
机构
[1] Okoinst CV, Rheinstr 95, D-64295 Darmstadt, Germany
[2] Tech Univ Darmstadt, Inst IWAR, Franziska Braun Str 7, D-64287 Darmstadt, Germany
[3] Leiden Univ, Inst Environm Sci, Leiden, Netherlands
[4] Delft Univ Technol, Dept Mat Sci & Engn, Delft, Netherlands
关键词
Rare earths; Molten salt electrolysis; Molten fluorides; Recycling; Ex-ante LCA; Perfluorocarbon (PFC) emissions; LIFE-CYCLE ASSESSMENT; ELEMENTS; PERFLUOROCARBONS; CONVERSION; FLUORIDES; EMISSIONS; RECOVERY; METALS; WASTE; OXIDE;
D O I
10.1007/s40831-018-0198-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A new recycling process for the extraction of rare earths from neodymium-iron-boron (NdFeB) magnet scrap is being developed, based on the direct extraction of rare earths from end-of-life magnet material in a molten fluoride electrolysis bath. Rare earths are required in their metallic form for the production of new NdFeB magnets, and the suggested process achieves this through a single step. The process is being developed on a laboratory scale and has been proven to work in principle. It is expected to be environmentally beneficial when compared to longer processing routes. Conducting life cycle assessment at R&D stage can provide valuable information to help steer process development into an environmentally favorable direction. We conducted a life cycle assessment study to provide a quantitative estimate of the impacts associated with the process being developed and to compare the prospective impacts against those of the current state-of-the-art technology. The comparison of this recycling route with primary production shows that the recycling process has the potential for much lower process-specific impacts when compared against the current rare earth primary production route. The study also highlights that perfluorocarbon emissions, which occur during primary rare earth production, warrant further investigation.
引用
收藏
页码:493 / 505
页数:13
相关论文
共 70 条
[1]   Neodymium extraction using salt extraction process [J].
Abbasalizadeh, A. ;
Teng, L. ;
Sridhar, S. ;
Seetharaman, S. .
TRANSACTIONS OF THE INSTITUTIONS OF MINING AND METALLURGY SECTION C-MINERAL PROCESSING AND EXTRACTIVE METALLURGY, 2015, 124 (04) :191-198
[2]  
Abbasalizadeh A, 2016, RARE EARTHS IND TECH
[3]   Electrochemical Extraction of Rare Earth Metals in Molten Fluorides: Conversion of Rare Earth Oxides into Rare Earth Fluorides Using Fluoride Additives [J].
Abbasalizadeh, Aida ;
Malfliet, Annelies ;
Seetharaman, Seshadri ;
Sietsma, Jilt ;
Yang, Yongxiang .
JOURNAL OF SUSTAINABLE METALLURGY, 2017, 3 (03) :627-637
[4]   Electrochemical Recovery of Rare Earth Elements from Magnets: Conversion of Rare Earth Based Metals into Rare Earth Fluorides in Molten Salts [J].
Abbasalizadeh, Aida ;
Malfliet, Annelies ;
Seetharaman, Seshadri ;
Sietsma, Jilt ;
Yang, Yongxiang .
MATERIALS TRANSACTIONS, 2017, 58 (03) :400-405
[5]  
Aluminum Association, 2013, ENV FOOTPR SEM AL PR
[6]  
[Anonymous], ILCD HDB INT REF LIF
[7]  
Bast U, 2015, RECYCLING KOMPONENTE
[8]   Recycling of rare earths: a critical review [J].
Binnemans, Koen ;
Jones, Peter Tom ;
Blanpain, Bart ;
Van Gerven, Tom ;
Yang, Yongxiang ;
Walton, Allan ;
Buchert, Matthias .
JOURNAL OF CLEANER PRODUCTION, 2013, 51 :1-22
[9]   Estimating perfluorocarbon emission factors for industrial rare earth metal electrolysis [J].
Cai, Bofeng ;
Liu, Helin ;
Kou, Fan ;
Yang, Youming ;
Yao, Bo ;
Chen, Xiping ;
Wong, David S. ;
Zhang, Lizhi ;
Li, Jianzhong ;
Kuang, Guochun ;
Chen, Liqu ;
Zheng, Jinwen ;
Guan, Dabo ;
Shan, Yuli .
RESOURCES CONSERVATION AND RECYCLING, 2018, 136 :315-323
[10]  
Elwert T, 2015, THESIS, DOI [10. 21268/20150513-093644, DOI 10.21268/20150513-093644]