Determination of reactivity ratios for ethylene/alpha-olefin copolymerization catalysed by the C2H4[Ind]2ZrCl2/methylaluminoxane system

被引：46
|
作者：
Galland, GB
Quijada, P
Mauler, RS
deMenezes, SC
机构：
[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT INGN QUIM,SANTIAGO,CHILE
[2] PETROBRAS SA,CENPES,DIQUIM,RIO JANEIRO,BRAZIL
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 09期
关键词：
D O I：
10.1002/marc.1996.030170901
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The present study reports values of reactivity ratios for ethylene/1-hexene, ethylene/1-octene and ethylene/1-decene copolymerizations promoted by C2H4[Ind]2ZrCl2/MAO. The comonomer reactivities are markedly influenced by the number of carbon atoms of the alpha-olefin. The ethylene/1-decene copolymerization depends on the concentration of alpha-olefin in the feed.
引用
收藏
页码：607 / 613
页数：7
相关论文
共 50 条
  • [31] Kinetic study of propylene polymerization using Et(H4Ind)2ZrCl2/methylalumoxane catalysts
    Univ of Waterloo, Waterloo, Ont, Canada
    Ind Eng Chem Res, 4 (1151-1157):
  • [32] In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)4/AlEt3-MAO/SiO2/ Et(Ind)2ZrCl2
    Guo, C. (cyguo@iccas.ac.cn), 1600, John Wiley and Sons Inc. (94):
  • [33] Preparation of Ethylene/Polyhedral Oligomeric Silsesquioxane(POSS) Copolymers with rac-Et(Ind)2ZrCl2/MMAO Catalyst System
    Lee, Dong-ho
    Yoon, Keun-byoung
    Jung, Myung-sung
    Sung, Jin-ki
    Noh, Seok Kyun
    PROGRESS IN OLEFIN POLYMERIZATION CATALYSTS AND POLYOLEFIN MATERIALS, PROCEEDINGS OF THE FIRST ASIAN POLYOLEFIN WORKSHOP, 2006, 161 : 53 - 58
  • [34] In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)4/AlEt3-MAO/SiO2/Et(Ind)2ZrCl2
    Zhu, BC
    Guo, CY
    Liu, ZY
    Yin, YQ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (06) : 2451 - 2455
  • [35] 导向配体辅助选择性合成rac-C2H4-（η5-Ind）2ZrCl2
    王岩
    马海燕
    华东理工大学学报(自然科学版), 2012, 38 (05) : 529 - 536+566
  • [36] Influence of Nanopores of MCM-41 and SBA-15 Confining (n-BuCp)2ZrCl2 on Copolymerization of Ethylene-α-Olefin
    Ko, Young Soo
    Lee, Jeong Suk
    Yim, Jin-Heong
    Jeon, Jong-Ki
    Jung, Kyeong Youl
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2010, 10 (01) : 180 - 185
  • [37] UV/visible spectroscopic study of the rac-Et(Ind)2ZrCl2/MAO olefin polymerization catalytic system, 2 -: Investigation in CH2Cl2
    Coevoet, D
    Cramail, H
    Deffieux, A
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1998, 199 (07) : 1459 - 1464
  • [38] ETHYLENE POLYMERIZATION INITIATED WITH THE CP2ZRCL2-METHYLALUMINOXANE CATALYST SYSTEM SUPPORTED ON ALPHA-CYCLODEXTRIN
    LEE, DH
    YOON, KB
    MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (11) : 841 - 843
  • [39] UV/visible spectroscopic study of the rac-Et(Ind)2ZrCl2/MAO olefin polymerization catalytic system, 1 -: Investigation in toluene
    Coevoet, D
    Cramail, H
    Deffieux, A
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1998, 199 (07) : 1451 - 1457
  • [40] Synthesis and characterization of copolymers of ethylene and 1-octadecene using the rac-Et(Ind)2ZrCl2/MAO catalyst system
    Quijada, R
    Narváez, A
    Rojas, R
    Rabagliati, FM
    Galland, GB
    Mauler, RS
    Benavente, R
    Pérez, E
    Pereña, JM
    Bello, A
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (06) : 1306 - 1310
12345