Determination of reactivity ratios for ethylene/alpha-olefin copolymerization catalysed by the C2H4[Ind]2ZrCl2/methylaluminoxane system

被引：46
|
作者：
Galland, GB
Quijada, P
Mauler, RS
deMenezes, SC
机构：
[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT INGN QUIM,SANTIAGO,CHILE
[2] PETROBRAS SA,CENPES,DIQUIM,RIO JANEIRO,BRAZIL
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 09期
关键词：
D O I：
10.1002/marc.1996.030170901
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The present study reports values of reactivity ratios for ethylene/1-hexene, ethylene/1-octene and ethylene/1-decene copolymerizations promoted by C2H4[Ind]2ZrCl2/MAO. The comonomer reactivities are markedly influenced by the number of carbon atoms of the alpha-olefin. The ethylene/1-decene copolymerization depends on the concentration of alpha-olefin in the feed.
引用
收藏
页码：607 / 613
页数：7
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