Determination of reactivity ratios for ethylene/alpha-olefin copolymerization catalysed by the C2H4[Ind]2ZrCl2/methylaluminoxane system

被引：46
|
作者：
Galland, GB
Quijada, P
Mauler, RS
deMenezes, SC
机构：
[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT INGN QUIM,SANTIAGO,CHILE
[2] PETROBRAS SA,CENPES,DIQUIM,RIO JANEIRO,BRAZIL
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 09期
关键词：
D O I：
10.1002/marc.1996.030170901
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The present study reports values of reactivity ratios for ethylene/1-hexene, ethylene/1-octene and ethylene/1-decene copolymerizations promoted by C2H4[Ind]2ZrCl2/MAO. The comonomer reactivities are markedly influenced by the number of carbon atoms of the alpha-olefin. The ethylene/1-decene copolymerization depends on the concentration of alpha-olefin in the feed.
引用
收藏
页码：607 / 613
页数：7
相关论文
共 50 条
  • [1] The influence of the comonomer in the copolymerization of ethylene with alpha-olefins using C2H4[Ind](2)ZrCl2/methylaluminoxane as catalyst system
    Quijada, R
    Galland, GB
    Mauler, RS
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (10) : 3091 - 3098
  • [2] Copolymerization of ethylene with ω-p-methylpenyl-α-olefin using Et(Ind)2ZrCl2/MAO as a catalyst
    Li Huayi
    Zhang Liaoyun
    Li Jinge
    Hu Youliang
    ACTA POLYMERICA SINICA, 2008, (04) : 371 - 377
  • [3] Copolymerization of Ethylene and Styrene Catalyzed via Supported Et(Ind)2ZrCl2
    Yan, Wei-Dong
    Zhang, Lei
    Zhou, Nai
    Hong, Han
    Hu, You-Liang
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 20 (02):
  • [4] Copolymerization of ethylene and styrene catalyzed via supported Et (Ind)2ZrCl2
    Yan, Wei-Dong
    Zhang, Lei
    Zhou, Nai
    Hong, Hen
    Hu, You-Liang
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 1999, 20 (02): : 321 - 323
  • [5] Copolymerization of ethylene and 1-hexene with Et(Ind)2ZrCl2 in hexane
    Britto, ML
    Galland, GB
    dos Santos, JHZ
    Forte, MC
    POLYMER, 2001, 42 (15) : 6355 - 6361
  • [6] Copolymerization of ethylene and styrene catalyzed via supported Et(Ind)2ZrCl2
    Yan, WD
    Zhang, L
    Zhou, N
    Hong, H
    Hu, YL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1999, 20 (02): : 321 - 323
  • [7] ELEMENTARY PROCESSES OF THE ZIEGLER CATALYSIS .7. ETHYLENE, ALPHA-OLEFIN AND NORBORNENE COPOLYMERIZATION WITH THE STEREORIGID CATALYST SYSTEMS IPR[FLUCP]ZRCL2/MAO AND ME2SI[IND]2ZRCL2/MAO
    HERFERT, N
    MONTAG, P
    FINK, G
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1993, 194 (11): : 3167 - 3182
  • [8] Copolymerization of ethylene and α-olefin using Et(Ind)2ZrCl2 entrapped inside the regular and small pores of MCM-41
    Ko, YS
    Woo, SI
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (05) : 739 - 744
  • [9] Copolymerization of ethylene and 1-hexene with in-situ supported Et[Ind]2ZrCl2
    Chu, KJ
    Shan, CLP
    Soares, JBP
    Penlidis, A
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (10) : 2372 - 2376
  • [10] Copolymerization of ethylene and hexene via silica-supported Me2(Ind)2ZrCl2
    Daqing Petroleum Inst, Heilongjiang, China
    Shiyou Huagong, 2 ([d]103-105):
12345