Synthesis of a quaternary polyprenyl ammonium salt

被引：6

作者：

Sizova, Olga V. ^{[1
]}

Utkina, Natalia S. ^{[1
]}

Kalinchuk, Nadezhda A. ^{[1
]}

Danilov, Leonid L. ^{[1
]}

Maltsev, Sergey D. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Kochetkov Lab Carbohydrate Chem, Moscow 119991, Russia

来源：

ACTA BIOCHIMICA POLONICA | 2007年 / 54卷 / 04期

关键词：

polyprenol; quaternary ammonium salts; cationic lipids;

D O I：

10.18388/abp.2007_3190

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Reaction of primary C-55-allylic alcohol moraprenol (WT3C7-9-OH, a polyprenol from mulberry leaves) with triethylamine in the presence of phosphorus oxychloride leads to a quaternary ammonium chloride with a good yield (72%) and high cis-stereoselectivity of the terminal isoprene unit. Cationic polyprenyl derivatives may be useful for transfection and immunological studies.

引用

页码：869 / 872

页数：4

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