The synthesis and photo-physical properties of extended styryl fluorescent derivatives of N-ethyl carbazole

被引:65
作者
Gupta, Vinod D. [1 ]
Padalkar, Vikas S. [1 ]
Phatangare, Kiran R. [1 ]
Patil, Vikas S. [1 ]
Umape, Prashant G. [1 ]
Sekar, N. [1 ]
机构
[1] Inst Chem Technol, Dyestuff Technol Dept, Bombay 400019, Maharashtra, India
关键词
Fluorescent dyes; Carbazole; Solid state fluorescence; Solvatochromism; Extended styryl dyes; Thermally stable dyes; Photo physics; NONLINEAR-OPTICAL PROPERTIES;
D O I
10.1016/j.dyepig.2010.08.013
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The solvatochromic behavior of novel carbazole containing dyes obtained by the condensation of 9-ethyl-9H-carbazole-3-carboxaldehyde and 9-ethyl-9H-carbazole-3 6-dicarboxaldehyde with (1-phenyl-ethylidene) propanedinitrile and ethyl-2-cyano-3-phenyl-2-butenoate are described The dyes were characterized by FT-IR H-1 NMR C-13 NMR Elemental analysis and Mass spectra DSC -TGA analysis showed these dyes are thermally stable up to 300 degrees C The UV-Vis absorption and fluorescence emission spectra of the dyes were studied in solvents of differing polarity the dyes exhibited positive solvatochromism and solvatofluorism (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:378 / 384
页数:7
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