A metal-carbene carbohydrate amphiphile as a low-molecular-mass organometallic gelator

被引：60
作者：
Bühler, G
Feiters, MC
Nolte, RJM
Dötz, KH
机构：
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
[2] Catholic Univ Nijmegen, Dept Organ Chem, NSRIM, NL-6525 ED Nijmegen, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 22期
关键词：
amphiphiles; carbene ligands; carbohydrates; chromium; gels;
D O I：
10.1002/anie.200351134
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stranded solvents: The aminocarbene chromium complex shown forms fiberlike aggregates of several μm length by self-assembly through noncovalent interactions. These strands allow an efficient immobilization of organic solvents in the form of a gel. The carbohydrate head group may induce supramolecular chirality in the aggregates.
引用
收藏
页码：2494 / 2497
页数：4
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