An extensive nonequilibrium steady-state kinetics model incorporating collisional and radiative processes is developed to study the electrical breakdown and discharge maintenance of laser-induced atmospheric plasma channels formed in externally applied electric fields. The model is based upon a self-consistent numerical solution of the Boltzmann equation for the electron energy distribution function coupled with the electron energy balance equation and the population balance equations for electrons and air species. Using the electron energy distribution function, the ionization and electron attachment rates as a function of the reduced applied electric field at different degrees of ionization are calculated. We find that the ionization rate as a function of applied electric field in a laser-induced plasma channel is orders of magnitude larger than that obtained for a natural atmospheric air discharge. Therefore, the electrical breakdown of these plasma channels may occur at significantly lower applied electric fields. The present model predicts a breakdown electric field of 10 kV/cm, while the experimentally determined breakdown field strength is similar to 5.7 kV/cm [A. P. Baronavski , NRL Memorandum Report No. NRL/MR/6110-02-8642, 2002 (unpublished)], a reduction of about a factor of 5 from the natural Paschen electrical breakdown field of similar to 30 kV/cm.
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MIT, Dept Chem, Cambridge, MA 02139 USA
MIT, Inst Soldier Nanotechnol, 77 Massachusetts Ave, Cambridge, MA 02139 USAMIT, Dept Chem, Cambridge, MA 02139 USA
Veysset, David
Maznev, A. A.
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MIT, Dept Chem, Cambridge, MA 02139 USA
MIT, Inst Soldier Nanotechnol, 77 Massachusetts Ave, Cambridge, MA 02139 USAMIT, Dept Chem, Cambridge, MA 02139 USA
Maznev, A. A.
Veres, Istvan A.
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Res Ctr Nondestruct Testing GmbH, Altenberger Str 69, A-4040 Linz, AustriaMIT, Dept Chem, Cambridge, MA 02139 USA
Veres, Istvan A.
Pezeril, Thomas
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Univ Maine, UMR CNRS 6283, Inst Mol & Mat Mans, F-72085 Le Mans, FranceMIT, Dept Chem, Cambridge, MA 02139 USA
Pezeril, Thomas
Kooi, Steven E.
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MIT, Dept Chem, Cambridge, MA 02139 USA
MIT, Inst Soldier Nanotechnol, 77 Massachusetts Ave, Cambridge, MA 02139 USAMIT, Dept Chem, Cambridge, MA 02139 USA
Kooi, Steven E.
Lomonosov, Alexey M.
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Heidelberg Univ, Inst Phys Chem, Neuenheimer Feld 253, D-69120 Heidelberg, GermanyMIT, Dept Chem, Cambridge, MA 02139 USA
Lomonosov, Alexey M.
Nelson, Keith A.
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MIT, Dept Chem, Cambridge, MA 02139 USA
MIT, Inst Soldier Nanotechnol, 77 Massachusetts Ave, Cambridge, MA 02139 USAMIT, Dept Chem, Cambridge, MA 02139 USA