Formation of Ti3Sn(1-x)AlxC2 Powder by Self-Propagating High Temperature Synthesis

被引：0

作者：

Xu, Jianguang ^{[1
]}

Gong, Chen ^{[1
]}

Cao, Kequan ^{[1
]}

Liu, Liang ^{[1
]}

Luo, Juhua ^{[1
]}

机构：

[1] Yancheng Inst Technol, Sch Mat Engn, Yancheng 224051, Peoples R China

来源：

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE | 2021年 / 30卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbides; lithium-ion storage property; self-propagating high temperature synthesis; Ti3SnC2; Ti2SnC; TI-C SYSTEM; MECHANICAL-PROPERTIES; SN; TI3ALC2; TI2SNC; PHASES; MICROSTRUCTURE; COMBUSTION; CARBIDE; TI3SIC2;

D O I：

10.1007/s11665-021-06393-w

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In the present study, high purity Ti3Sn(1-x)AlxC2 solid solution was successfully synthesized by Self-propagating high temperature synthesis (SHS) from Ti-Sn-Al-C reactants. Al plays a key role during the reaction process, which can replace Sn atom to form unstable Ti2Al(1-y)SnyC or Ti3Sn(1-x)AlxC2 solid solutions. Ti2Al(1-y)SnyC is likely to transform to Ti3Sn(1-x)AlxC2 at high temperature, and the unstable Ti3Sn(1-x)AlxC2 phase has been kept because the SHS reaction would suddenly completed in a few minutes. Otherwise, Ti2SnC is the dominant phase if the reactants only contain Ti, Sn and C powders. TiC and Sn are also appeared as second phases because Ti2SnC would like to decompose at high temperatures. Moreover, Ti3Sn(1-x)AlxC2 showed promising capability in lithium-ion storage.

引用

页码：9008 / 9014

页数：7

共 35 条

[1] Chemical bonding and elastic properties of Ti3AC2 phases (A = Si, Ge, and Sn): A first-principle study [J].

Bai, Yuelei ;

He, Xiaodong ;

Sun, Yue ;

Zhu, Chuncheng ;

Li, Mingwei ;

Shi, Liping .

SOLID STATE SCIENCES, 2010, 12 (07) :1220-1225

[2] Elastic and Mechanical Properties of the MAX Phases [J].

Barsoum, Michel W. ;

Radovic, Miladin .

ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 41, 2011, 41 :195-227

[3] QUANTITATIVE INTERPRETATION OF X-RAY-DIFFRACTION PATTERNS OF MIXTURES .1. MATRIX-FLUSHING METHOD FOR QUANTITATIVE MULTICOMPONENT ANALYSIS [J].

CHUNG, FH .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1974, 7 (DEC1) :519-525

[4]

Dean JA, 1998, LANGES HDB CHEM, P29

[5] A new ternary nanolaminate carbide:: Ti3SnC2 [J].

Dubois, Sylvain ;

Cabioc'h, Thierry ;

Chartier, Patrick ;

Gauthier, Veronique ;

Jaouen, Michel .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (08) :2642-2644

[6] Synthesis, Microstructure, and Mechanical Properties of Ti3Sn(1-x)AlxC2 MAX Phase Solid Solutions [J].

Dubois, Sylvain ;

Bei, Guo P. ;

Tromas, Christophe ;

Gauthier-Brunet, Veronique ;

Gadaud, Pascal .

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2010, 7 (06) :719-729

[7] The Mn+1AXn phases: Materials science and thin-film processing [J].

Eklund, Per ;

Beckers, Manfred ;

Jansson, Ulf ;

Hogberg, Hans ;

Hultman, Lars .

THIN SOLID FILMS, 2010, 518 (08) :1851-1878

[8] Optimization of the Ti3SiC2 MAX phase synthesis [J].

El Saeed, M. A. ;

Deorsola, F. A. ;

Rashad, R. M. .

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2012, 35 :127-131

[9] Synthesis and characterization of Hf2PbC, Zr2PbC and M2SnC (M = Ti, Hf, Nb or Zr) [J].

El-Raghy, T ;

Chakraborty, S ;

Barsoum, MW .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (14-15) :2619-2625

[10] Formation mechanism for synthesis of Ti3SnC2 MAX phase [J].

Fattahi, Mehdi ;

Mehrizi, Majid Zarezadeh .

MATERIALS TODAY COMMUNICATIONS, 2020, 25

← 1 2 3 4 →