Novel 'quinolone' metal complexes:: Synthesis and spectroscopic studies of Mg(II), Zn(II) and Ba(II) complexes with N-methyl (or NH)-3-acetyl-4-hydroxy quinolin-2-one ligands

被引：8

作者：

Athanasellis, G

Gavrielatos, E

Igglessi-Markopoulou, O

Markopoulos, J ^{[2
]}

机构：

[1] Natl Tech Univ Athens, Dept Chem Engn, Organ Chem Lab, Athens 15773, Greece

[2] Univ Athens, Dept Chem, Inorgan Chem Lab, Athens 15771, Greece

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2003年 / 40卷 / 04期

关键词：

D O I：

10.1002/jhet.5570400413

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The complexation between N-methyl-3-acetyl-4-hydroxyquinolin-2-one (NMeQuin) and N-H-3-acetyl-4-hydroxy quinolin-2-one (NHQuin) with MgCl2, ZnCl2 and BaCl2 has been accomplished. The structure of the resulting complexes 1-5 has been elucidated through elemental analyses, Fr-IR and H-1/C-13 NMR Spectroscopy and Mass Spectrometry. The spectroscopic data show complexes of the general formula Mg-2(OH)L-3(H2O)(z) and ML2(H2O)(z) where: M = Zn(11) and Ba(11), L = NMeQuin, NHQuin and z = 2,4.

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页码：645 / 648

页数：4

相关论文

共 24 条

[1]

ATHANASELLIS G, 2000, 34 INT C COORD CHEM, P14

[2] 4-HYDROXY-3-QUINOLINECARBOXAMIDES WITH ANTIARTHRITIC AND ANALGESIC ACTIVITIES [J].

CLEMENCE, F ;

LEMARTRET, O ;

DELEVALLEE, F ;

BENZONI, J ;

JOUANEN, A ;

JOUQUEY, S ;

MOUREN, M ;

DERAEDT, R .

JOURNAL OF MEDICINAL CHEMISTRY, 1988, 31 (07) :1453-1462

[3] Reactions of 2-methyl-3,1-benzoxazin-4-one with active methylene compounds: A new route to 3-substituted 4-hydroxyquinolin-2(1H)-ones [J].

Detsi, A ;

Bardakos, V ;

Markopoulos, J ;

IgglessiMarkopoulou, O .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (24) :2909-2913

[4]

FERRARO JR, 1971, LOW FREQUENCY VIBRAT, P75

[5] Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues. Crystal structure of [Cu(abta)2(py)2]&middot2H2O [J].

Gavrielatos, Efstathios ;

Mitsos, Christos ;

Athanasellis, Giorgos ;

Heaton, Brian T. ;

Steiner, Alexander ;

Bickley, Jamie F. ;

Igglessi-Markopoulou, Olga ;

Markopoulos, John .

2001, Royal Society of Chemistry

[6] INHIBITION OF HUMAN ERYTHROCYTE CALPAIN-I BY NOVEL QUINOLINE CARBOXAMIDES [J].

GRAYBILL, TL ;

DOLLE, RE ;

OSIFO, IK ;

SCHMIDT, SJ ;

GREGORY, JS ;

HARRIS, AL ;

MILLER, MS .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1995, 5 (04) :387-392

[7] 5-HT3 RECEPTOR ANTAGONISTS .2. 4-HYDROXY-3-QUINOLINECARBOXYLIC ACID-DERIVATIVES [J].

HAYASHI, H ;

MIWA, Y ;

ICHIKAWA, S ;

YODA, N ;

MIKI, I ;

ISHII, A ;

KONO, M ;

YASUZAWA, T ;

SUZUKI, F .

JOURNAL OF MEDICINAL CHEMISTRY, 1993, 36 (05) :617-626

[8] Rhodium(I) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and the crystal structure of [Rh(abta){P(OPh)(3)}(2)] [J].

Heaton, BT ;

Jacob, C ;

Markopoulos, J ;

Markopoulou, O ;

Nahring, J ;

Skylaris, CK ;

Smith, AK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (08) :1701-1706

[9] Novel 5-amino-6-methylquinolone antibacterials: A new class of non-6-fluoroquinolones [J].

Hong, CY ;

Kim, SH ;

Kim, YK .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1997, 7 (14) :1875-1878

[10] SYNTHESIS AND STRUCTURES OF VOLATILE MONONUCLEAR AND PENTANUCLEAR CHELATES OF BARIUM [J].

HUANG, L ;

TURNIPSEED, SB ;

HALTIWANGER, RC ;

BARKLEY, RM ;

SIEVERS, RE .

INORGANIC CHEMISTRY, 1994, 33 (04) :798-803