Emulsion polymerization of styrene and vinyl acetate with cationic surfactant

被引：2

作者：

Erkal, Durdane

Senkal, B. Filiz ^{[1
]}

Sarac, Ayfer

机构：

[1] Bahcesehir Univ, Fac Arts & Sci, TR-34100 Istanbul, Turkey

[2] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

[3] Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey

来源：

MACROMOLECULAR SYMPOSIA | 2007年 / 254卷

关键词：

emulsion polymerization; lattices; stabilization; surfactants;

D O I：

10.1002/masy.200750822

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this study, the emulsion homopolymerization system containing vinyl acetate and styrene, potassium persulfate, and a new cationic surfactant was studied in the classical glass emulsion polymerization reactor. The effects of new polymeric emulsifier on the physicochemical properties of obtained vinyl acetate and styrene latex properties were investigated depending on surfactant percentage in homopolymerizations.

引用

收藏

页码：141 / 145

页数：5

相关论文

共 20 条

[1] THE STABILIZATION EFFECT OF MIXED-SURFACTANTS IN THE EMULSION POLYMERIZATION OF STYRENE [J].

CHU, HH ;

PIIRMA, I .

POLYMER BULLETIN, 1989, 21 (03) :301-308

[2] Stabilizing effect of the cationic surfactant (CPB) in emulsion polymerization [J].

Chu, HH ;

Hwang, HY .

POLYMER BULLETIN, 1997, 38 (03) :295-302

[3] Emulsion polymerization of styrene using conventional, polymerizable, and polymeric surfactants. A comparative study [J].

Cochin, D ;

Laschewsky, A ;

Nallet, F .

MACROMOLECULES, 1997, 30 (08) :2278-2287

[4]

EMELIE B, 1991, MAKROMOL CHEM, V192, P1629

[5]

Emelie B., 1985, MAKROMOL CHEM S, V10, P43

[6] THE DETERMINANTS OF LATEX MONODISPERSITY IN EMULSION POLYMERIZATIONS [J].

FEENEY, PJ ;

NAPPER, DH ;

GILBERT, RG .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 118 (02) :493-505

[7] Miniemulsion polymerization with cationic and nonionic surfactants: A very efficient use of surfactants for heterophase polymerization [J].

Landfester, K ;

Bechthold, N ;

Tiarks, F ;

Antonietti, M .

MACROMOLECULES, 1999, 32 (08) :2679-2683

[8] SURFACTANT EFFECTS IN THE EMULSION POLYMERIZATION OF VINYL-ACETATE [J].

LEE, CH ;

MALLINSON, RG .

JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 39 (11-12) :2205-2218

[9] LYOTROPIC LIQUID-CRYSTALLINE PHASE-BEHAVIOR OF AMPHIPHILIC MONOMERS AND POLYMERS HAVING A ROD-LIKE HYDROPHOBIC MOIETY [J].

LUHMANN, B ;

FINKELMANN, H .

COLLOID AND POLYMER SCIENCE, 1987, 265 (06) :506-516

[10] VISCOSITY - MOLECULAR WEIGHT RELATIONSHIP FOR POLYVINYL ACETATE [J].

MATSUMOTO, M ;

OHYANAGI, Y .

JOURNAL OF POLYMER SCIENCE, 1960, 46 (148) :441-454