Modelling of RP chromatographic systems

被引：4

作者：

Kwietniewski, L ^{[1
]}

Janicka, M ^{[1
]}

Rozylo, JK ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland

来源：

CHROMATOGRAPHIA | 2000年 / 52卷 / 9-10期

关键词：

column liquid chromatography; thermodynamic description of retention; modelling chromatographic systems;

D O I：

10.1007/BF02789750

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper continues studies on the use of Oscik's equation-assuming an adsorption-partitioning mechanism of chromatography in reversed-phase liquid chromatography. The equation describes the relationship between solute retention and mobile phase composition, including four parameters characterising the chromatographic system. Model theoretical studies on the effect of molecular interactions, surface phase composition and solute properties on retention are presented.

引用

页码：559 / 563

页数：5

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