Tetracene Dicarboxylic Imide and Its Disulfide: Synthesis of Ambipolar Organic Semiconductors for Organic Photovoltaic Cells

被引：42

作者：

Okamoto, Toshihiro ^{[2
]}

Suzuki, Tsuyoshi ^{[2
]}

Tanaka, Hideyuki ^{[2
]}

Hashizume, Daisuke ^{[1
]}

Matsuo, Yutaka ^{[2
]}

机构：

[1] RIKEN, Adv Technol Support Div, Wako, Saitama 3510198, Japan

[2] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2012年 / 7卷 / 01期

基金：

日本科学技术振兴机构;

关键词：

ambipolar compounds; disulfides; organic photovoltaic cells; semiconductors; tetracene; THIN-FILM TRANSISTORS; FIELD-EFFECT TRANSISTORS; HIGH-ELECTRON-MOBILITY; HIGH-PERFORMANCE; COMPLEMENTARY CIRCUITS; DIIMIDE DERIVATIVES; TRANSPORT; ACENES; PENTACENE; STABILITY;

D O I：

10.1002/asia.201100590

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have designed and synthesized a new donor/acceptor-type tetracene derivative by the introduction of dicarboxylic imide and disulfide groups as electron-withdrawing and -donating units, respectively. The prepared compounds, tetracene dicarboxylic imide (TI) and its disulfide (TIDS) have high chemical and electrochemical stability as well as long-wavelength absorptions of up to 886 nm in the thin films. The crystal packing structure of TIDS molecules features face-to-face p-stacking, derived from dipoledipole interactions. Notably, TIDS exhibited ambipolar properties of both electron-donating and -accepting natures in pn and pin heterojunction organic thin-film photovoltaic devices. Accordingly, TI and TIDS are expected to be promising compounds for designing new organic semiconductors.

引用

页码：105 / 111

页数：7

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