Comparison of the synergistic inhibition mechanism of two eco-friendly amino acids combined corrosion inhibitors for carbon steel pipelines in oil and gas production

被引:79
作者
Zhang, Q. H. [1 ]
Li, Y. Y. [1 ]
Lei, Y. [1 ]
Wang, X. [1 ]
Liu, H. F. [1 ,2 ]
Zhang, G. A. [1 ]
机构
[1] Huazhong Univ Sci & Technol, Key Lab Mat Chem Energy Convers & Storage, Hubei Key Lab Mat Chem & Serv Failure, Sch Chem & Chem Engn,Minist Educ, Wuhan 430074, Peoples R China
[2] Huazhong Univ Sci & Technol, State Key Lab Coal Combust, Wuhan 410074, Peoples R China
关键词
Carbon steel; Corrosion inhibitors; Adsorption; Synergism; QUATERNARY AMMONIUM-SALTS; MILD-STEEL; CO2; CORROSION; PYRIMIDINE-DERIVATIVES; COPPER CORROSION; SCHIFF-BASE; THIOUREA; BEHAVIOR; ADSORPTION; PROTECTION;
D O I
10.1016/j.apsusc.2022.152559
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The combination of corrosion inhibitors is a significant method to enhance the inhibitive effects of inhibitors owing to their synergism. In this work, the inhibition synergism of two eco-friendly amino acids (L-histidine, L-cysteine) and thiourea on the corrosion of N80 carbon steel in CO2-containing environment was studied by electrochemical tests and surface analysis. The results indicate that the combination of L-histidine/L-cysteine and thiourea could synergistically boost the inhibition performance of L-histidine/L-cysteine and thiourea, i.e., present a remarkable inhibition synergism. Moreover, the synergism mechanism is in-depth revealed by theoretical calculations. The stronger interaction between L-histidine and thiourea accounts for the better synergistic inhibition effect.
引用
收藏
页数:17
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