Self-assembly in gold(I) chemistry: A double-stranded polymer with interstrand aurophilic interactions

被引：60

作者：

Mohr, F ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 08期

关键词：

gold; macrocycles; polymers; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Raising the gold standard: Hybrid organic-inorganic side-by-side double-chain polymers have been prepared in which individual polymer chains are connected through the aurophilic interactions of gold (1) centers (see picture). The use of alternative isomers of the monomeric building blocks leads to the formation of dimeric or trimeric complexes.

引用

页码：969 / 971

页数：3

共 19 条

[1] Crystal structure of the antiarthritic drug gold thiomalate (myochrysine): A double-helical geometry in the solid state [J].

Bau, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (36) :9380-9381

[2] Co-ordination and conformational isomerism in bis(tricyclohexylphosphine) gold(I) halides [J].

Bowmaker, GA ;

Brown, CL ;

Hart, RD ;

Healy, PC ;

Rickard, CEF ;

White, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (06) :881-889

[3] Do aurophilic interactions compete against hydrogen bonds?: Experimental evidence and rationalization based on ab initio calculations [J].

Codina, A ;

Fernández, EJ ;

Jones, PG ;

Laguna, A ;

López-De-Luzuriaga, JM ;

Monge, M ;

Olmos, ME ;

Pérez, J ;

Rodríguez, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (23) :6781-6786

[4] Aurophilicity-based one-dimensional arrays of gold(I) phenylene-1,3-and-1,4-dithiolates [J].

Ehlich, H ;

Schier, A ;

Schmidbaur, H .

INORGANIC CHEMISTRY, 2002, 41 (14) :3721-3727

[5] Forty-five years of chemical discovery including a golden quarter-century [J].

Fackler, JP .

INORGANIC CHEMISTRY, 2002, 41 (26) :6959-6972

[6] A Gold(I) mononuclear complex and its association into binuclear and cluster compounds by hydrogen bonding or metal ion coordination [J].

Hao, LJ ;

Mansour, MA ;

Lachicotte, RJ ;

Gysling, HJ ;

Eisenberg, R .

INORGANIC CHEMISTRY, 2000, 39 (24) :5520-5529

[7]

Howe BP, 1998, QUIM NOVA, V21, P564

[8] Complexes derived from 4-(diphenylphosphino)benzoic acid and related ligands that contain mixed-metal assemblies of palladium(II) or gold(I) in combination with the multiply bonded dirhenium(II) unit [J].

Kuang, SM ;

Fanwick, PE ;

Walton, RA .

INORGANICA CHIMICA ACTA, 2002, 338 :219-227

[9] A new type of tweezer complex involving a rhenium-rhenium multiple bond that enforces an unusual structure in a dipalladium(II) unit [J].

Kuang, SM ;

Fanwick, PE ;

Walton, RA .

INORGANIC CHEMISTRY, 2002, 41 (05) :1036-1038

[10] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

← 1 2 →