High performance zinc-bromine redox flow batteries: Role of various carbon felts and cell configurations

被引：52
作者：
Suresh, S. [1 ,2 ]
Ulaganathan, M. [1 ,2 ]
Venkatesan, N. [2 ]
Periasamy, P. [1 ,2 ]
Ragupathy, P. [1 ,2 ]
机构：
[1] Acad Sci & Innovat Res, CSIR Campus, New Delhi, India
[2] CSIR Cent Electrochem Res Inst CECRI, Flow Battery Sect, Electrochem Power Sources Div, Karaikkudi 630003, Tamil Nadu, India
来源：
JOURNAL OF ENERGY STORAGE | 2018年 / 20卷
关键词：
Zinc bromine; Flow battery; Carbon felt; Efficiency; SUPERIOR ELECTRODE;
D O I：
10.1016/j.est.2018.09.006
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Optimization of the cell configuration utilizing various carbon felts for obtaining better performance in zincbromine redox flow battery (ZBRFB) system is reported. It is clearly observed that the reaction kinetics of both Zn and Br are enhanced when used in different cell configurations with carbon felts. Redox flow cells having carbon felts on both half-cells showed improved performance thanthe other cell configurations tested in the present study. Further, Rayon based carbon felt is evaluated as an electrode on both sides. It is noted that the Rayon carbon felt based cell exhibited good performance in terms of coulombic (96.26%), voltaic (83%) and energy efficiency (79.4%) at a current density of 20 mA.cm(-2). In addition to that, Rayon felt based system showed good performance even at 40 mA.cm(-2) (3250 mW h. l(-1)) which indicates the significance of the flow cell configuration on the overall cell performance.
引用
收藏
页码：134 / 139
页数：6
相关论文
共 31 条
[1]   Suppressing Dendrite Growth during Zinc Electrodeposition by PEG-200 Additive [J].
Banik, Stephen J. ;
Akolkar, Rohan .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (11) :D519-D523
[2]   A symmetric organic-based nonaqueous redox flow battery and its state of charge diagnostics by FTIR [J].
Duan, Wentao ;
Vemuri, Rama S. ;
Milshtein, Jarrod D. ;
Laramie, Sydney ;
Dmello, Rylan D. ;
Huang, Jinhua ;
Zhang, Lu ;
Hu, Dehong ;
Vijayakumar, M. ;
Wang, Wei ;
Liu, Jun ;
Darling, Robert M. ;
Thompson, Levi ;
Smith, Kyle ;
Moore, Jeffery S. ;
Brushett, Fikile R. ;
Wei, Xiaoliang .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (15) :5448-5456
[3]   A REVIEW OF MATHEMATICAL-MODELING OF THE ZINC BROMINE FLOW CELL AND BATTERY [J].
EVANS, TI ;
WHITE, RE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (11) :2725-2733
[4]   All-Soluble All-Iron Aqueous Redox-Flow Battery [J].
Gong, Ke ;
Xu, Fei ;
Grunewald, Jonathan B. ;
Ma, Xiaoya ;
Zhao, Yun ;
Gu, Shuang ;
Yan, Yushan .
ACS ENERGY LETTERS, 2016, 1 (01) :89-93
[5]  
Harris F.W., 1930, 57 GEN M AM EL SOC S
[6]   Review of zinc-based hybrid flow batteries: From fundamentals to applications [J].
Khor, A. ;
Leung, P. ;
Mohamed, M. R. ;
Flox, C. ;
Xu, Q. ;
An, L. ;
Wills, R. G. A. ;
Morante, J. R. ;
Shah, A. A. .
MATERIALS TODAY ENERGY, 2018, 8 :80-108
[7]   A novel single flow zinc-bromine battery with improved energy density [J].
Lai, Qinzhi ;
Zhang, Huamin ;
Li, Xianfeng ;
Zhang, Liqun ;
Cheng, Yuanhui .
JOURNAL OF POWER SOURCES, 2013, 235 :1-4
[8]   Transparent conducting ZnO:Al, In and Sn thin films deposited by the sol-gel method [J].
Lee, JH ;
Park, BO .
THIN SOLID FILMS, 2003, 426 (1-2) :94-99
[9]   Zinc deposition and dissolution in methanesulfonic acid onto a carbon composite electrode as the negative electrode reactions in a hybrid redox flow battery [J].
Leung, P. K. ;
Ponce-de-Leon, C. ;
Low, C. T. J. ;
Walsh, F. C. .
ELECTROCHIMICA ACTA, 2011, 56 (18) :6536-6546
[10]   High Performance Vanadium Redox Flow Batteries with Optimized Electrode Configuration and Membrane Selection [J].
Liu, Q. H. ;
Grim, G. M. ;
Papandrew, A. B. ;
Turhan, A. ;
Zawodzinski, T. A. ;
Mench, M. M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (08) :A1246-A1252
1234