Thalia dealbata Inspired Anisotropic Cellular Biomass Derived Carbonaceous Aerogel

被引:54
作者
Chen, Tao [1 ,2 ]
Zhang, Jian [1 ]
Shi, Peiheng [2 ]
Li, Yi [1 ]
Zhang, Ling [1 ,2 ]
Sun, Zhengzong [3 ,4 ]
He, Rong [1 ,2 ]
Duan, Tao [1 ,2 ]
Zhu, Wenkun [1 ,2 ,5 ]
机构
[1] Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat & Biom, 59 Qinglong Ave, Mianyang, Sichuan 621010, Peoples R China
[2] Southwest Univ Sci & Technol, Nucl Waste & Environm Safety Key Lab Def, 59 Qinglong Ave, Mianyang 621010, Sichuan, Peoples R China
[3] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[4] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[5] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Konjac glucomannan; Graphene oxide; Aerogel; Bionic structure; Sensor; Supercapacitors; HIGHLY EFFICIENT; GRAPHENE OXIDE; STRAIN SENSOR; ULTRA-LIGHT; IN-SITU; SUPERELASTICITY; PERFORMANCE; LIGHTWEIGHT; KONJAC; FOAM;
D O I
10.1021/acssuschemeng.8b04528
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon aerogels with biomimetic structures have shown excellent physicochemical properties and brought great potential applications to a wide range of fields. The utilization of renewable resources as the carbon precursors offers a low-cost and scalable way to fabricate biomimetic carbon aerogels with intriguing properties such as ultralight weight, superelasticity, and high conductivity. Inspired by the unique hierarchical mineral bridge structure of Thalia dealbata stem, we fabricated an ultralight, superelastic, highly conductive carbon aerogel (KGA) by using konjac glucomannan and graphene oxide as the carbon precursors. The unique mineral-bridged layered structure not only endows the carbon aerogel with a low density of 4.2 mg cm(-3) but also a high electrical conductivity (12.9 S m(-1)). In addition, the carbon aerogel also exhibits a superelastic property of 80% maximal strain and no obvious degradation after 1000 cycles of compression. We demonstrated that this Thalia dealbata inspired carbon aerogel has potential applications in supercapacitor electrodes and piezoresistive sensors.
引用
收藏
页码:17152 / 17159
页数:15
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