Tylenol® and Aspirin® as Green Promoters for Ipso-Hydroxylation of Arylboronic Acids

被引：2

作者：

Kwon, Gyu-Tae ^{[1
]}

Kim, Seung-Hoi ^{[1
]}

机构：

[1] Dankook Univ, Dept Chem, 119 Dandaero, Cheonan 31116, South Korea

来源：

LETTERS IN ORGANIC CHEMISTRY | 2022年 / 19卷 / 10期

关键词：

TYLENOL (R); ASPIRIN (R); green promoters; ipso-hydroxylation; arylboronic acids; phenols; AEROBIC OXIDATIVE HYDROXYLATION; ARYL/HETEROARYL BORONIC ACIDS; HIGHLY EFFICIENT CONVERSION; VISIBLE-LIGHT; HETEROGENEOUS CATALYST; ORGANIC FRAMEWORK; PHENOLS; METAL; MILD; TRANSFORMATIONS;

D O I：

10.2174/1570178618666210907164813

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We explored the most expedient pathway for phenolic compound preparation using a combination of arylboronic acids, a green oxidant (H2O2) and a catalytic amount of readily available medicinal materials (TYLENOL (R) and ASPIRIN (R)). The arylboronic acids were successfully transformed into the corresponding phenols in high yields under metal- and base-free aqueous aerobic conditions. We demonstrated that enhanced availability and sustainability are some advantages associated with the use of medicinal supports.

引用

页码：902 / 907

页数：6

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