High entropy oxides: The role of entropy, enthalpy and synergy

被引:241
作者
Sarkar, Abhishek [1 ,2 ,3 ]
Ben Breitung [3 ]
Hahn, Horst [1 ,2 ,3 ,4 ,5 ]
机构
[1] Tech Univ Darmstadt, Joint Res Lab Nanomat, D-64287 Darmstadt, Germany
[2] Karlsruhe Inst Technol, D-64287 Darmstadt, Germany
[3] Karlsruhe Inst Technol KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[4] Univ Calif Irvine, Dept Mat Sci & Engn, Irvine, CA USA
[5] Nanjing Univ Sci & Technol, Herbert Gleiter Inst Nanosci, Nanjing, Peoples R China
基金
欧盟地平线“2020”;
关键词
Multicomponent equiatomic systems; High entropy ceramics; Entropy-stabilization; Functional properties; RARE-EARTH; DISTORTION; CATALYSTS; ALLOYS; CO;
D O I
10.1016/j.scriptamat.2020.05.019
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This viewpoint article focuses on some of the important issues related to the emerging field of high entropy oxides (HEOs). Open queries regarding the role of entropy, enthalpy, individual elements and synergy arising from the presence of multiple elements in HEOs are discussed. In addition, a brief overview of the current state of research on HEOs is provided. Finally, we share our views on the uniqueness of HEOs by describing some features, which distinguish them from the conventional oxides. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:43 / 48
页数:6
相关论文
共 74 条
[1]   Phase stability and distortion in high-entropy oxides [J].
Anand, G. ;
Wynn, Alex P. ;
Handley, Christopher M. ;
Freeman, Colin L. .
ACTA MATERIALIA, 2018, 146 :119-125
[2]   Low temperature synthesis and characterization of single phase multi-component fluorite oxide nanoparticle sols [J].
Anandkumar, Mariappan ;
Bhattacharya, Saswata ;
Deshpande, Atul Suresh .
RSC ADVANCES, 2019, 9 (46) :26825-26830
[3]   Mechanochemical Synthesis of (Co,Cu,Mg,Ni,Zn)O High-Entropy Oxide and Its Physicochemical Properties [J].
Balcerzak, Mateusz ;
Kawamura, Kenichi ;
Bobrowski, Rafal ;
Rutkowski, Pawel ;
Brylewski, Tomasz .
JOURNAL OF ELECTRONIC MATERIALS, 2019, 48 (11) :7105-7113
[4]   Controlled Jahn-Teller distortion in (MgCoNiCuZn)O-based high entropy oxides [J].
Berardan, D. ;
Meena, A. K. ;
Franger, S. ;
Herrero, C. ;
Dragoe, N. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 704 :693-700
[5]   Room temperature lithium superionic conductivity in high entropy oxides [J].
Berardan, D. ;
Franger, S. ;
Meena, A. K. ;
Dragoe, N. .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (24) :9536-9541
[6]   Colossal dielectric constant in high entropy oxides [J].
Berardan, David ;
Franger, Sylvain ;
Dragoe, Diana ;
Meena, Arun Kumar ;
Dragoe, Nita .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2016, 10 (04) :328-333
[7]  
Bergfeldt T., 2020, ELECTROCHEMISTRY, V1, P60, DOI [10.3390/electrochem1010007, DOI 10.3390/ELECTROCHEM1010007]
[8]   Synthesis and sintering of (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxides obtained by wet chemical methods [J].
Biesuz, Mattia ;
Spiridigliozzi, Luca ;
Dell'Agli, Gianfranco ;
Bortolotti, Mauro ;
Sglavo, Vincenzo M. .
JOURNAL OF MATERIALS SCIENCE, 2018, 53 (11) :8074-8085
[9]   Nanostructured multi-element (TiZrNbHfTa)N and (TiZrNbHfTa)C hard coatings [J].
Braic, V. ;
Vladescu, Alina ;
Balaceanu, M. ;
Luculescu, C. R. ;
Braic, M. .
SURFACE & COATINGS TECHNOLOGY, 2012, 211 :117-121
[10]   Charge-Induced Disorder Controls the Thermal Conductivity of Entropy-Stabilized Oxides [J].
Braun, Jeffrey L. ;
Rost, Christina M. ;
Lim, Mina ;
Giri, Ashutosh ;
Olson, David H. ;
Kotsonis, George N. ;
Stan, Gheorghe ;
Brenner, Donald W. ;
Maria, Jon-Paul ;
Hopkins, Patrick E. .
ADVANCED MATERIALS, 2018, 30 (51)