Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)]

被引：1
|
作者：
Chang, Jian-Guo [1 ]
机构：
[1] Taishan Univ, Dept Mat Sci & Chem Engn, Tai An 271021, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
mean σ(C-C) = 0.003 Å; R factor = 0.026; single-crystal X-ray study; T = 298 K; wR factor = 0.064; data-to-parameter ratio = 13.4;
D O I：
10.1107/S1600536811050720
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O ',N-tridentate ligand and a pyridine molecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu-O bond.
引用
收藏
页码：M1886 / U732
页数：11
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