Bis{μ-4-chloro-N′-[(E)-1-(5-chloro-2-oxidophenyl)ethylidene]benzohydrazidato}bis[pyridinecopper(II)]

被引：1
|
作者：
Chang, Jian-Guo [1 ]
机构：
[1] Taishan Univ, Dept Mat Sci & Chem Engn, Tai An 271021, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
mean σ(C-C) = 0.003 Å; R factor = 0.026; single-crystal X-ray study; T = 298 K; wR factor = 0.064; data-to-parameter ratio = 13.4;
D O I：
10.1107/S1600536811050720
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is pentacoordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O ',N-tridentate ligand and a pyridine molecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu-O bond.
引用
收藏
页码：M1886 / U732
页数：11
相关论文
共 50 条
  • [1] Ammonium bis{3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}ferrate(III)methanol solvate
    Mizuguchi, Jin
    Sato, Yohei
    Uta, Kazuya
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1327 - M1328
  • [2] 4-Chloro-N '-[(E)-2-chlorobenzylidene]-benzohydrazide monohydrate
    Mague, Joel T.
    Mohamed, Shaaban K.
    Akkurt, Mehmet
    Potgieter, Herman
    Albayati, Mustafa R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O612 - +
  • [3] Bis(μ-4-chlorobenzoato)bis[(4-chloro-benzoato) bis(1H-imidazole-κN3)cadmium(II)]dihydrate
    Guo, Xian-Xia
    Yan, Jian-Bin
    Song, Wen-Dong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1305 - U48
  • [4] Ammonium bis{3-anilinocarbonyl-1-[(5-chloro-2oxidophenyl)diazenyl]-2-naphtholato}ferrate(III)acetone solvate
    Mizuguchi, Jin
    Uta, Kazuya
    Sato, Yohei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1329 - M1330
  • [5] Bis[(2-chloro-4-fluorobenzyl) triphenylphosphonium] bis(1,2,5-thiadiazole-3,4-dithiolato) nickelate(II)
    Zeng, Zhou-Hua
    Yang, Shui-Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M239 - U348
  • [6] {4-Bromo-2-[(5-chloro-2-oxidophenyl)iminomethyl]phenolato-κ3O,N,O′}-(methanol-κO)(methanolato-κO)oxidovanadium(V)
    Shahverdizadeh, Gholam Hossein
    Ng, Seik Weng
    Tiekink, Edward R. T.
    Mirtamizdoust, Babak
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M221 - U1285
  • [7] (N',N '' Z,N',N '' E)-N',N ''-[1-(4-Chloro-phenyl)ethane-1,2-diylidene]bis(3-methyl-1-benzofuran-2-carbohydrazide)
    Fun, Hoong-Kun
    Chia, Tze Shyang
    Alafeefy, Ahmed M.
    Abdel-Aziz, Hatem A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02405 - +
  • [8] 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
    Abu Affan, Md.
    Chee, Dayang N. A.
    Ahmad, Fasihuddin B.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O555 - U4471
  • [9] Bis{6-bromo-4-chloro-2-[(E)-(2-chlorophenyl)iminomethyl] phenolato-kappa(2) N,O}copper(II)
    Ping, Zhang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1118 - +
  • [10] (1E,2E)-1,2-Bis[1-(3-nitrophenyl)ethylidene]hydrazine
    Asik, Safra Izuani Jama
    Fun, Hoong-Kun
    Razak, Ibrahim Abdul
    Jansrisewangwong, Patcharaporn
    Chantraproma, Suchada
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O643 - U1671
12345