Efficient Sunlight-Driven Dehydrogenative Coupling of Methane to Ethane over a Zn+-Modified Zeolite

被引：179

作者：

Li, Lu ^{[1
,2
]}

Li, Guo-Dong ^{[2
]}

Yan, Chang ^{[2
]}

Mu, Xiao-Yue ^{[2
]}

Pan, Xiao-Liang ^{[2
]}

Zou, Xiao-Xin ^{[2
]}

Wang, Kai-Xue ^{[1
]}

Chen, Jie-Sheng ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preperat Chem, Coll Chem, Changchun 130012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 36期

关键词：

C-H activation; electron transfer; photocatalysis; zeolites; zinc; DIRECT CONVERSION; ACTIVATION; SPECTROSCOPY; OXIDATION; CHEMICALS; FUELS; SITES;

D O I：

10.1002/anie.201102320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sun bath: A Zn+-modified zeolite catalyst showing superior photocatalytic activity for the activation of a C-H bond converted methane into ethane and hydrogen upon irradiation of sunlight (see picture). Light at wavelengths shorter than 390 nm transferred electrons from the zeolite framework to the zinc centers. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8299 / 8303

页数：5

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