Green synthesis of polymers using supercritical carbon dioxide

被引：64
作者：
Wood, CD
Cooper, AI
DeSimone, JM
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] Univ Liverpool, Dept Chem, Donnan & Robert Robinson Labs, Liverpool L69 3BX, Merseyside, England
[3] N Carolina State Univ, Dept Chem Engn, Raleigh, NC 27695 USA
来源：
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 2004年 / 8卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
supercritical; fluoropolymer; porous polymers; high-throughput;
D O I：
10.1016/j.cossms.2005.02.001
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Supercritical carbon dioxide is the most extensively studied supercritical fluid (SCF) medium for polymerization reactions and organic transformations. This can be attributed to a list of advantages ranging from solvent properties to practical environmental as well as economic considerations. Aside from these gains, CO2 finds particularly advantageous application in the synthesis and processing of fluoropolymers and porous materials and as such, this will be the subject of this review. The overall aim is to highlight areas where the unique properties of SCF solvents can be exploited to generate polymers that would be difficult or inconvenient to obtain by other routes. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：325 / 331
页数：7
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