RETRACTED: Hydrolysis of biomass using a reusable solid carbon acid catalyst and fermentation of the catalytic hydrolysate to ethanol

被引:39
作者
Goswami, Mandavi [1 ]
Meena, S. [1 ]
Navatha, S. [2 ]
Rani, K. N. Prasanna [2 ]
Pandey, Ashok [1 ]
Sukumaran, Rajeev Kumar [1 ]
Prasad, R. B. N. [2 ]
Devi, B. L. A. Prabhavathi [2 ]
机构
[1] CSIR Natl Inst Interdisciplinary Sci & Technol, Div Biotechnol, Ctr Biofuels, Thiruvananthapuram 695019, Kerala, India
[2] CSIR Indian Inst Chem Technol, Ctr Lipid Res, Hyderabad 500007, Andhra Pradesh, India
关键词
Solid acid catalyst; Bioethanol; Enzymatic hydrolysis; Catalytic hydrolysis; Fermentation; BEARING SO3H; COOH;
D O I
10.1016/j.biortech.2015.03.012
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Solid acid catalysts can hydrolyze cellulose with lower reaction times and are easy to recover and reuse. A glycerol based carbon acid catalyst developed at CSIR-IICT performed well in acid catalysis reactions and hence this study was undertaken to evaluate the catalyst for hydrolysis of biomass (alkali pretreated or native rice straw). The catalyst could release 262 mg/g total reducing sugars (TRS) in 4 h at 140 degrees C from alkali pretreated rice straw, and more importantly it released 147 mg/g TRS from native biomass. Reusability of the catalyst was also demonstrated. Catalytic hydrolysate was used as sugar source for fermentation to produce ethanol. Results indicate the solid acid catalyst as an interesting option for biomass hydrolysis. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:99 / 102
页数:4
相关论文
共 17 条
[1]   A Glycerol-based Carbon Catalyst for the Preparation of Biodiesel [J].
Devi, Bethala L. A. Prabhavathi ;
Gangadhar, Katkam N. ;
Prasad, Potharaju S. Sai ;
Jagannadh, Bulusu ;
Prasad, Rachapudi B. N. .
CHEMSUSCHEM, 2009, 2 (07) :617-620
[2]   Comparative evaluation of autohydrolysis and acid-catalyzed hydrolysis of Eucalyptus globulus wood [J].
Guetsch, Jenny Sabrina ;
Nousiainen, Tiia ;
Sixta, Herbert .
BIORESOURCE TECHNOLOGY, 2012, 109 :77-85
[3]   Solid acid mediated hydrolysis of biomass for producing biofuels [J].
Guo, Feng ;
Fang, Zhen ;
Xu, C. Charles ;
Smith, Richard L., Jr. .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2012, 38 (05) :672-690
[4]   A carbon material as a strong protonic acid [J].
Hara, M ;
Yoshida, T ;
Takagaki, A ;
Takata, T ;
Kondo, JN ;
Hayashi, S ;
Domen, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2955-2958
[5]   Bioconversion of lignocellulose: inhibitors and detoxification [J].
Jonsson, Leif J. ;
Alriksson, Bjorn ;
Nilvebrant, Nils-Olof .
BIOTECHNOLOGY FOR BIOFUELS, 2013, 6
[6]   Adsorption-Enhanced Hydrolysis of β-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO3H, COOH, and OH Groups [J].
Kitano, Masaaki ;
Yamaguchi, Daizo ;
Suganuma, Satoshi ;
Nakajima, Kiyotaka ;
Kato, Hideki ;
Hayashi, Shigenobu ;
Hara, Michikazu .
LANGMUIR, 2009, 25 (09) :5068-5075
[7]   Efficiencies of acid catalysts in the hydrolysis of lignocellulosic biomass over a range of combined severity factors [J].
Lee, Jae-Won ;
Jeffries, Thomas W. .
BIORESOURCE TECHNOLOGY, 2011, 102 (10) :5884-5890
[8]   USE OF DINITROSALICYLIC ACID REAGENT FOR DETERMINATION OF REDUCING SUGAR [J].
MILLER, GL .
ANALYTICAL CHEMISTRY, 1959, 31 (03) :426-428
[9]   Hydrolysis of cellulose into glucose over carbons sulfonated at elevated temperatures [J].
Pang, Jifeng ;
Wang, Aiqin ;
Zheng, Mingyuan ;
Zhang, Tao .
CHEMICAL COMMUNICATIONS, 2010, 46 (37) :6935-6937
[10]  
Ruiz R., 1996, Determination of Carbohydrates in Biomass by High Performance Liquid Chromatography