Study of formation of cobalt and zinc phosphates in solvothermal synthesis using piperazine and 2-methylpiperazine as templating molecules.: Structure investigations of [C4H8N2H4][(Co0.44(1)Zn0.56(1))2(PO4)(H1.5PO4)2] and of [C5N2H14][(Co0.25(3)Zn0.75(3))(HPO4)2]

被引：24
作者：
Christensen, AN [1 ]
Bareges, A
Nielsen, RB
Hazell, RG
Norby, P
Hanson, JC
机构：
[1] Aarhus Univ, Dept Inorgan Chem, DK-8000 Aarhus C, Denmark
[2] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
[3] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 10期
关键词：
D O I：
10.1039/b009677f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds [C4H8N2H4][Zn-2(PO4)(H1.5PO4)(2)], [C4H8N2H4][(Co0.44(1)Zn0.56(1))(2)(PO4)(H1.5PO4)(2)], [C5N2H14][Zn(HPO4)(2)] and [C5N2H14][(Co0.25(3)Zn0.75(3))(HPO4)(2)] were obtained in solvothermal synthesis using piperazine or 2-methylpiperazine as templating molecules. Syntheses were made in Teflon-lined pressure vessels at temperatures up to 190 degreesC and the crystallization processes were investigated by real time in situ measurements of synchrotron X-ray powder diffraction patterns at temperatures up to 200 degreesC.
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页码：1611 / 1615
页数：5
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