Synthesis and Crystal Structure of Nickel Complex Assembled from Pyridine-Carboxylate Ligand

被引：0
|
作者：
Yang, Min
Zhang, Xiuling
Zhu, Baoyong
机构：
来源：
ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 05期
关键词：
Coordination polymer; Hydrothermal synthesis; Crystal structure; Pyridine-carboxylate ligand; COORDINATION POLYMERS; 3-PYRID-3-YLBENZOIC ACID;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The pyridine carboxylato-bridged coordination polymer [Ni(3,3-pbc)(2)(H(2)O)(2)](n) (3,3-pbc=3-pyrid-3-ylbenzoic acid) has been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single crystal X-ray analyses reveal that the carboxylate groups of 3,3-pbc ligand adopt one coordinated mode: bis-monodentate (mu(2)-eta(1):eta(1)) and bidentate chelating (mu(1)-eta(1):eta(1)) fashion. Hydrogen bonding interactions are found in compound which further extend and stabilize the coordination motifs.
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页码：2131 / 2133
页数：3
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