Failure analysis of a copper tube in a finned heat exchanger

This paper reports on the failure analysis of a finned heat exchanger which leaked in the pressure test during commissioning. The heat exchanger was composed of panels made of thin-walled copper tubes and aluminum fins, and the structure was typical of equipment used in the heating, ventilation and air-conditioning industry. The tube material was phosphorus deoxidized copper Cu-DHP. In the pressure test, one of the tubes was found to have three leakage points. The investigation showed that the failure was a consequence of ant-nest corrosion, as all the experimental findings, together with the copper grade and the tube dimensions, were typical of this corrosion mechanism. Corrosion had initiated from the outer surface of the tube. The paper presents the morphology of the failure using optical and scanning electron microscope (SEM) micrographs. The presence of a contaminating organic substance on the outer tube surface and inside the corrosion crack was verified by SEM/EDS analyses. The corrosion mechanism and the relevant chemical reactions given in the literature are summarized, and the conditions in which the failure may occur are presented. Ant-nest corrosion is a special form of local corrosion, and associated most often with deoxidized copper tubes used in heat transfer applications as in this study. (C) 2015 Elsevier Ltd. All rights reserved.