NMR Study of Synthetic Gallosilicate Natrolite

被引：1

作者：

Paczwa, M. ^{[1
]}

Sapiga, A. A. ^{[2
]}

Olszewski, M. ^{[1
]}

Sapiga, A., V ^{[2
]}

Sergeev, N. A. ^{[1
]}

机构：

[1] Univ Szczecin, Inst Phys, Dept Math & Phys, Szczecin, Poland

[2] VI Vernadsky Crimean Fed Univ, Phys Tech Inst, Simferopol 295007, Russia

来源：

APPLIED MAGNETIC RESONANCE | 2020年 / 51卷 / 01期

关键词：

ZEOLITES; RELAXATION; DIFFUSION; GALLIUM; NUCLEI;

D O I：

10.1007/s00723-019-01163-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Solid-state Si-29 and Ga-71 NMR was used to study the synthetic gallosilicate Na16Ga16Si24O80 16H(2)O (Ga-natrolite). It has been shown that Ga-natrolite contains mainly Si(GaO4)(3)(SiO4) and Si(GaO4)(2)(SiO4)(2)-structural units and has sufficiently ordered structure. Temperature dependence of the spin-lattice relaxation time T-1 of Ga-71 nuclei has also been studied using solid-state NMR. Spin-lattice relaxation of the Ga-71 was determined to be governed by the electric quadrupole interaction with the crystal electric field gradients modulated by translational motion of H2O molecules in the Ga-natrolite pores.

引用

页码：33 / 40

页数：8

共 25 条

[11] In situ disorder-order transformation in synthetic gallosilicate zeolites with the NAT topology
Hong, SB
Lee, SH
Shin, CH
Woo, AJ
Alvarez, LJ
Zicovich-Wilson, CM
Camblor, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) : 13742 - 13751
[12] INVESTIGATION OF THE STRUCTURE OF ZEOLITES BY SOLID-STATE HIGH-RESOLUTION SI-29 NMR-SPECTROSCOPY
LIPPMAA, E
MAGI, M
SAMOSON, A
TARMAK, M
ENGELHARDT, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) : 4992 - 4996
[13] Modelling one- and two-dimensional solid-state NMR spectra
Massiot, D
Fayon, F
Capron, M
King, I
Le Calvé, S
Alonso, B
Durand, JO
Bujoli, B
Gan, ZH
Hoatson, G
[J]. MAGNETIC RESONANCE IN CHEMISTRY, 2002, 40 (01) : 70 - 76
[14] Meier W.M., 1960, Zeitschrift fur Kristallographie, V113, P430
[15] Nagy J. B., 2007, MOL SIEVES, V5, P365, DOI DOI 10.1007/3829_006
[16] Newsam M., 1992, SOLID STATE CHEM COM, P234
[17] 27Al NMR Study of the Structure and Dynamics of Natrolite
Paczwa, M.
Sapiga, A. A.
Olszewski, M.
Sergeev, N. A.
Sapiga, A. V.
[J]. APPLIED MAGNETIC RESONANCE, 2015, 46 (05) : 583 - 592
[18] IONIC AND MOLECULAR-DIFFUSION AND THE ORDER-DISORDER PHASE-TRANSITION IN THE THALLIUM FORM OF NATROLITE
PANICH, AM
BELITSKII, IA
MOROZ, NK
GABUDA, SP
DREBUSHCHAK, VA
SERETKIN, YV
[J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1990, 31 (01) : 56 - 63
[19] NMR study of gallosilicate natrolite
Sapiga, A. A.
Olszewski, M.
Paczwa, M.
Sapiga, A., V
Sergeev, N. A.
[J]. FUNCTIONAL MATERIALS, 2014, 21 (02): : 181 - 185
[20] Sapiga A. V., 2003, THESIS

← 1 2 3 →