Ligand free green plasma-in-liquid synthesis of Au/Ag alloy nanoparticles

被引:11
作者
Cempel, David [1 ]
Mai Thanh Nguyen [1 ]
Ishida, Yohei [1 ]
Tokunaga, Tomoharu [2 ]
Yonezawa, Tetsu [1 ]
机构
[1] Hokkaido Univ, Fac Engn, Div Mat Sci & Engn, Kita Ku, Kita 13 Nishi 8, Sapporo, Hokkaido 0608628, Japan
[2] Nagoya Univ, Dept Mat Sci & Engn, Fac Engn, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan
关键词
D O I
10.1039/c7nj05154a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Au/Ag alloy nanoparticles (NPs) were successfully prepared by a one step synthesis using HAuCl4 and [Ag(NH3)(2)](+) as the corresponding precursors in a microwave-induced plasma in liquid process (MWPLP) without the addition of any organic protecting or reducing agents. The time dependent reduction and particle formation during the 140 min plasma discharge were studied with TEM, UV-vis extinction spectra, and ICP-OES. After 140 min, the HAADF-STEM and EDX results indicated that the obtained Au/Ag NPs were alloy NPs. Varying the input molar ratios of the metal precursors allowed for control of the composition of the Au/Ag alloy NPs.
引用
收藏
页码:5681 / U9
页数:8
相关论文
共 55 条
[1]   Magnetic and noble metal nanocomposites for separation and optical detection of biological species [J].
Bagga, K. ;
Brougham, D. F. ;
Keyes, T. E. ;
Brabazon, D. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (42) :27968-27980
[2]   Optical properties and relaxation processes at femtosecond scale of bimetallic clusters [J].
Broyer, M. ;
Cottancin, E. ;
Lerme, J. ;
Pellarin, M. ;
Del Fatti, N. ;
Vallee, F. ;
Burgin, J. ;
Guillon, C. ;
Langot, P. .
FARADAY DISCUSSIONS, 2008, 138 :137-145
[3]   L-Arginine-Stabilized Highly Uniform Ag Nanoparticles Prepared in a Microwave-Induced Plasma-in-Liquid Process (MWPLP) [J].
Cempel, David ;
Mai Thanh Nguyen ;
Ishida, Yohei ;
Yonezawa, Tetsu .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2018, 91 (03) :362-367
[4]   Au Nanoparticles Prepared Using a Coated Electrode in Plasma-in-Liquid Process: Effect of the Solution pH [J].
Cempel, David ;
Mai Thanh Nguyen ;
Ishida, Yohei ;
Tsukamoto, Hiroki ;
Shirai, Hiroaki ;
Wang, Yongming ;
Wu, Kevin C. -W. ;
Yonezwa, Tetsu .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (09) :9257-9262
[5]   A review of plasma-liquid interactions for nanomaterial synthesis [J].
Chen, Qiang ;
Li, Junshuai ;
Li, Yongfeng .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2015, 48 (42)
[6]   Controllable Catalysis with Nanoparticles: Bimetallic Alloy Systems and Surface Adsorbates [J].
Chen, Tianyou ;
Rodionov, Valentin O. .
ACS CATALYSIS, 2016, 6 (06) :4025-4033
[7]   Synthesis of silver-gold alloy nanoparticles by a phase-transfer system [J].
Chimentao, RJ ;
Cota, I ;
Dafinov, A ;
Medina, F ;
Sueiras, JE ;
de la Fuente, JLG ;
Fierro, JLG ;
Cesteros, Y ;
Salagre, P .
JOURNAL OF MATERIALS RESEARCH, 2006, 21 (01) :105-111
[8]   Effect of composition and packing configuration on the dichroic optical properties of coinage metal nanorods [J].
Cortie, M. B. ;
Xu, X. ;
Ford, M. J. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (30) :3520-3527
[9]   COAGULATION OF COLLOIDAL GOLD [J].
ENUSTUN, BV ;
TURKEVICH, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (21) :3317-+
[10]   Tailoring the particle size of monodispersed colloidal gold [J].
Goia, DV ;
Matijevic, E .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 146 (1-3) :139-152