Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions

被引：28

作者：

Cui, Xue ^{[1
]}

Ma, Hongzhu ^{[1
]}

Wang, Bo ^{[1
]}

Chen, Hongwei ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Coll Chem & Mat Sci, Inst Energy Chem, Xian 710062, Peoples R China

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2007年 / 147卷 / 03期

关键词：

sulfated tin oxide catalysts; modified; n-Heptane; catalytic oxidation;

D O I：

10.1016/j.jhazmat.2007.01.118

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The direct oxidation of n-heptane to ester using air as the oxidant under mild conditions assisted by sulfated tin oxide (SO42-/SnO2) and Co modified sulfated tin oxide (SO42- /SnO2-Co2O3) prepared by chemical co-precipitation method and characterized by means of SEM, XRD, FT-IR and XPS techniques was studied. From the results it was found that the catalytic activity Of SO42-/SnO2-Co2O3 is higher than that Of SO42-/SnO2 in this target reaction, and two asymmetric esters: diisobutyl phthalate and cyclohexylmethyl tridecyl oxalate that have not been reported in the directly oxidation of n-heptane by traditional method have been obtained. The possible mechanism was also discussed. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：800 / 805

页数：6

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