Chemoenzymatic synthesis of the two enantiomers of 7-azatryptophan

被引：18
|
作者：
Lecointe, L [1 ]
Rolland-Fulcrand, V [1 ]
Roumestant, ML [1 ]
Viallefont, P [1 ]
Martinez, J [1 ]
机构：
[1] Univ Montpellier 1&2, Lab Aminoacides Peptides & Prot, F-34095 Montpellier 5, France
来源：
TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 10期
关键词：
D O I：
10.1016/S0957-4166(98)00130-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
7-Azatryptophan is an unnatural alpha-amino acid with a very potent fluorescent activity. It is used as a vehicle for probing the structure and dynamics of proteins and peptides. Diastereoselective alkylation, diastereoselective protonation and enzymatic resolution have been tested for preparing enantiomerically pure 7-azatryptophan. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1753 / 1758
页数：6
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