Bridged aminotroponiminate complexes of zinc

被引：0

作者：

Gamer, MT ^{[1
]}

Roesky, PW ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 11期

关键词：

aminotroponiminate; coordination chemistry; N ligands; zinc;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the n-propyl-bridged diaminotroponimine H-2{(iPr)TP} with dialkylzinc compounds in toluene lead, depending on the stoichiometric ratio, either to dimetallic singly bridged products of composition [(RZn)(2){(iPr)TP}] [R = Me (1), Et (2)] or to dimetallic doubly bridged helical products of composition [Zn{(iPr)TP}](2) (3). Compound 3, which was characterised by single-crystal diffraction methods, is the first bridged aminotroponiminate complex in which a helical structure is observed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

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收藏

页码：2145 / 2148

页数：4

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