Bridged aminotroponiminate complexes of zinc

被引：0
|
作者：
Gamer, MT [1 ]
Roesky, PW [1 ]
机构：
[1] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 11期
关键词：
aminotroponiminate; coordination chemistry; N ligands; zinc;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of the n-propyl-bridged diaminotroponimine H-2{(iPr)TP} with dialkylzinc compounds in toluene lead, depending on the stoichiometric ratio, either to dimetallic singly bridged products of composition [(RZn)(2){(iPr)TP}] [R = Me (1), Et (2)] or to dimetallic doubly bridged helical products of composition [Zn{(iPr)TP}](2) (3). Compound 3, which was characterised by single-crystal diffraction methods, is the first bridged aminotroponiminate complex in which a helical structure is observed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
引用
收藏
页码：2145 / 2148
页数：4
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