A Heterotetranuclear Metal Complex {Ni2Na2} with Azido Bridges

被引：13
作者：
Ge, Cheng-Min [1 ]
Zhang, Shu-Hua [1 ]
Feng, Chao [1 ]
Wang, Yin-Guang [1 ]
Li, Wei [1 ]
机构：
[1] Guilin Univ Technol, Coll Chem & Bioengn, Key Lab Nonferrous & Mat Proc Technol, Minist Educ, Guilin 541004, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 01期
关键词：
Heterotetranuclear; Defective dicubane; Solvothermal synthesis; Magnetic properties; END-TO-END; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; LIGANDS; CHAIN; COPPER(II); TRANSITION; CLUSTERS; BEHAVIOR; IONS;
D O I：
10.1002/zaac.201000217
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Ni(ClO4)(2)center dot 6H(2)O with 3-ethoxy-2-hydroxy-benzaldehyde (Hemp), methylamine, and NaN3 in DMF solution, under solvothermal conditions, leads to the formation of the heterotetrametallic cluster [Ni2Na2(mu(1,1,1)-N-3)(2)(emimp)(4)(DMF)(2)] (I) (emimp = 2-ethoxy-6-formyl-phenolate anion, DMF = N,N-dimethyl-formamide). Compound I displays dominant ferromagnetic interactions through mu(1,1,1)-N-3 bridging mode.
引用
收藏
页码：112 / 116
页数：5
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