Ligand-free, atom-efficient Suzuki-Miyaura type cross-coupling reactions at room temperature

被引：37
|
作者：
Zhou, Wen-Jun [1 ]
Wang, Ke-Hu [1 ]
Wang, Jin-Xian [1 ,2 ]
Gao, Zhi-Rong [1 ]
机构：
[1] NW Normal Univ, Inst Chem, Dept Chem, Lanzhou 730070, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
TETRAHEDRON | 2010年 / 66卷 / 38期
关键词：
ASYMMETRIC ALDOL REACTIONS; ARYL BOND FORMATION; SODIUM TETRAPHENYLBORATE; POLYETHYLENE-GLYCOL; MICHAEL ADDITION; PALLADIUM CATALYSTS; RECYCLABLE REACTION; ARYLBORONIC ACIDS; SOLVENT-FREE; C-C;
D O I：
10.1016/j.tet.2010.07.022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The atom-efficient cross-coupling reaction of sodium tetraarylborates with aryl iodides and bromides was reported. The reaction can be performed directly using a catalytic system composed of palladium chloride, sodium carbonate and methanol (PdCl2/Na2CO3/MeOH) under heat-free conditions at room temperature in an open air conditions. The reactions carried out in an atom-efficient way as 4 equiv of aryl halides coupled effectively with 1 equiv of sodium tetraarylborates to furnish 4 equiv of the corresponding functionalized biaryls in good to excellent yields. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7633 / 7641
页数：9
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