New Development in Rare Earth Metal Complexes Containing Anionic Bis(imino)pyrrolyl and Bis(phosphanyl)amide Ligands

被引：15

作者：

Li, Tianshu ^{[1
]}

Jenter, Jelena ^{[1
]}

Roesky, Peter W. ^{[1
]}

机构：

[1] Karlsruher Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 12期

关键词：

Rare earth elements; N ligands; Coordination compounds; Catalysis; Chelates; HOMOLEPTIC LANTHANIDE COMPLEXES; RING-OPENING POLYMERIZATION; X-RAY-STRUCTURE; CYCLOPENTADIENYL COMPLEXES; INSERTION REACTIONS; YTTRIUM COMPLEXES; PRE-CATALYST; REACTIVITY; ISOPRENE; YTTERBIUM;

D O I：

10.1002/zaac.201000169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rare earth element complexes with the very bulky 2,5bis{N-(2,6-diisopropylphenyl)iminomethyl} pyrrolyl and the sterically less demanding bis(phosphanyl)amide ligand, (PPh2)(2)N- in the coordination sphere are reviewed in this research report. The coordination chemistry, the reactivity, and the catalytic application of the corresponding complexes are discussed.

引用

页码：2148 / 2155

页数：8

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