New Development in Rare Earth Metal Complexes Containing Anionic Bis(imino)pyrrolyl and Bis(phosphanyl)amide Ligands

被引：15
作者：
Li, Tianshu [1 ]
Jenter, Jelena [1 ]
Roesky, Peter W. [1 ]
机构：
[1] Karlsruher Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 12期
关键词：
Rare earth elements; N ligands; Coordination compounds; Catalysis; Chelates; HOMOLEPTIC LANTHANIDE COMPLEXES; RING-OPENING POLYMERIZATION; X-RAY-STRUCTURE; CYCLOPENTADIENYL COMPLEXES; INSERTION REACTIONS; YTTRIUM COMPLEXES; PRE-CATALYST; REACTIVITY; ISOPRENE; YTTERBIUM;
D O I：
10.1002/zaac.201000169
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rare earth element complexes with the very bulky 2,5bis{N-(2,6-diisopropylphenyl)iminomethyl} pyrrolyl and the sterically less demanding bis(phosphanyl)amide ligand, (PPh2)(2)N- in the coordination sphere are reviewed in this research report. The coordination chemistry, the reactivity, and the catalytic application of the corresponding complexes are discussed.
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收藏
页码：2148 / 2155
页数：8
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