On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals

被引：1172

作者：

Pan, Jian ^{[1
]}

Liu, Gang ^{[1
]}

Lu, Gao Qing ^{[2
]}

Cheng, Hui-Ming ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

[2] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 09期

关键词：

crystal growth; heterogeneous catalysis; hydrothermal synthesis; photochemistry; titania; SOLAR-CELLS; SURFACE; NANOCRYSTALS; PHOTOCATALYSIS; NANOPARTICLES; PERCENTAGE; WATER;

D O I：

10.1002/anie.201006057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Contrary to conventional understanding, clean anatase {001} facets exhibit lower photoreactivity than {101} facets. Furthermore, the {010} facets showed the highest photocatalytic reactivity in generating OH radicals and hydrogen evolution. This behavior was revealed by studies on crystals grown hydrothermally to have a predominance of {001}, {101}, or {010} facets (left to right in picture(a) and (b)-(d), respectively). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2133 / 2137

页数：5

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