Inclusion and separation of lutidine isomers by a diol host compound

被引：9

作者：

Caira, MR

Horne, A

Nassimbeni, LR ^{[1
]}

Toda, F

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 790, Japan

来源：

SUPRAMOLECULAR CHEMISTRY | 1998年 / 9卷 / 03期

关键词：

inclusion; separation; lutidines;

D O I：

10.1080/10610279808034991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structures of the inclusion compounds formed between the host compound 1,1-bis(4-hydroxyphenyl)cyclohexane and selected lutidine isomers have been elucidated. The activation energies and kinetics of desolvation for the complexes were determined. Competition experiments were performed to investigate preferential enclathration. Lattice energy calculations explain the results of the competition experiments.

引用

页码：231 / 237

页数：7

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