Partial hydrogenation of 1,3-cyclooctadiene using dendrimer-encapsulated Pd-Rh bimetallic nanoparticles

被引：84

作者：

Chung, YM ^{[1
]}

Rhee, HK ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem Engn, Inst Chem Proc, Seoul 151742, South Korea

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 206卷 / 1-2期

关键词：

dendrimer; nanoreactor; nanoparticle; bimetal; organic-inorganic composite; hydrogenation;

D O I：

10.1016/S1381-1169(03)00418-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article reports the first effort for the preparation of Pd-Rh bimetallic nanoparticles in the presence of poly(amidoamine) dendrimers with surface hydroxyl groups (fourth generation, PAMAM-OH). The resulting dendrimer-encapsulated Pd-Rh bimetallic nanoparticles show a promising catalytic activity in partial hydrogenation of 1,3-cyclooctadiene. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：291 / 298

页数：8

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