Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands:: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(η2-C2H4)2{κ3N,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4′-(S)-isopropyloxazolin-2′-yl)pyridine)

被引：20
作者：
Díez, J [1 ]
Gamasa, MP [1 ]
Gimeno, J [1 ]
Paredes, P [1 ]
机构：
[1] Univ Oviedo, Dept Quim Organ & Inorgan, Inst Quim Organometal Enrique Moles, Fac Quim,Unidad Asoc CSIC, E-33071 Oviedo, Spain
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 08期
关键词：
D O I：
10.1021/om050073x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel iridium(I)-pybox complexes [Ir(Ln)(n)-{kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] (n = 2, L = eta(2)-C2H4 (1), eta(2)-MeO2CC CCO2Me (2); n = 1, L = CO (3)) have been synthesized. The treatment of complex 1 with HCl or allyl chloride under very mild conditions results in the stereoselective formation of the complexes [IrClH(eta(2)-C2H4){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] (4) and [IrCl(eta(3)-C3H5){(KN)-N-3,N,N-(S,S)-i-Pr-pybox}][PF6] (5). The structures of complexes 1 and 5 have been determined by X-ray diffraction analyses.
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页码：1799 / 1802
页数：4
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