Electromigration and complexing in reactions of reduction of cations

被引：0
|
作者：
Kharkats, YI [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 1998年 / 34卷 / 06期
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D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In the system sustaining complexing reactions, mass transfer frequently becomes intensified. This effect takes place in reactions in which multicharged cations undergo complexing with negatively charged ligands and which yield positively charged complex ions of a lesser charge. The electrodiffusion problem is studied theoretically in a system with the complex formation for which kinetic Butler-Volmer equations are true.
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页码：526 / 531
页数：6
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