Conductance studies on complex formation of nano Cu(NO3)2.2.5H2O with 4,6-diacetylresorcinol in mixed solvents

被引：7

作者：

Sanad, Sameh G. ^{[1
]}

Shebl, Magdy ^{[1
]}

机构：

[1] Ain Shams Univ, Fac Educ, Dept Chem, Cairo, Egypt

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 294卷

关键词：

Formation thermodynamic parameters; Formation constants; Gibbs free energy; Enthalpy; Entropy; Nano copper nitrate; 4,6-Diacetylresorcinol; BINUCLEAR METAL-COMPLEXES; TERNARY COPPER(II) COMPLEXES; DNA-BINDING; ANTIMICROBIAL ACTIVITY; STRUCTURAL DIVERSITY; AQUEOUS-SOLUTION; SPECTROSCOPIC CHARACTERIZATION; STABILITY-CONSTANTS; LIGAND COMPLEXES; CARBOXYLIC-ACIDS;

D O I：

10.1016/j.molliq.2019.111602

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The different complexation thermodynamic parameters for example, formation constants (K-f), free energies of formation (Delta G(f)) enthalpies of formation (Delta H-f) and entropies of formation (Delta S-f) for nano copper nitrate hemi pentahydrate (Cu(NO3)(2).2.5H(2)O) with 4,6-diacetylresorcinol as a ligand in pure DMF and in mixed solvents of DMF and water are calculated at different temperatures, 293.15, 303.15, 313.15 and 323.15 K by using conductance measurements. By drawing the relation between molar conductance and ratio of metal to ligand, the figures indicate the formation of two types of complexes with M:L ratios 1:2 and 1:1 stoichiometric complexes. (C) 2019 Elsevier B.V. All rights reserved.

引用

页数：9

共 76 条

[71] EFFECT OF PRESSURE ON DIMERIZATION OF CARBOXYLIC-ACIDS IN AQUEOUS-SOLUTION [J].