Neutral and Anionic Transition-Metal-Base-Stabilized Metalloborylene Complexes

被引：13

作者：

Braunschweig, Holger ^{[1
]}

Kraft, Katharina ^{[1
]}

Oestreicher, Sebastian ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 35期

关键词：

boron; borylene complexes; coordination chemistry; platinum; transition metals; TERMINAL BORYLENE COMPLEXES; BRIDGING LIGAND; BORON; COORDINATION; REACTIVITY; CHEMISTRY;

D O I：

10.1002/chem.201001368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Time for T-shaped metalloborylenes: The first anionic trinuclear metal boron complex and a neutral analogue have been prepared and fully characterized. The unusual T-shaped geome-try renders the title compounds, transition-metal-base-stabilized metalloborylenes, which became available by an unprecedented direct synthetic approach. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10635 / 10637

页数：3

共 45 条

[11] Terminal borylene complexes stabilized by a transition-metal base [J].

Braunschweig, H ;

Rais, D ;

Uttinger, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (24) :3763-3766

[12] Preparation and structural characterization of transition metal complexes featuring the ferrocenyl(bromo)boryl ligand [J].

Braunschweig, H ;

Radacki, K ;

Rais, D ;

Seeler, F .

ORGANOMETALLICS, 2004, 23 (23) :5545-5549

[13]

Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P4198, DOI 10.1002/1521-3773(20011119)40:22<4198::AID-ANIE4198>3.0.CO

[14]

2-E

[15]

Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P2298, DOI 10.1002/1521-3773(20010618)40:12<2298::AID-ANIE2298>3.0.CO

[16]

2-E

[17]

Braunschweig H., 2005, ANGEW CHEM, V117, P3829

[18]

Braunschweig H., 2007, ANGEW CHEM, V119, P7932

[19]

Braunschweig H., 2001, ANGEW CHEM, V113, P4327

[20]

BRAUNSCHWEIG H, 2008, ANGEW CHEM, V120, P5009

← 1 2 3 4 5 →