Neutral and Anionic Transition-Metal-Base-Stabilized Metalloborylene Complexes

被引：13

作者：

Braunschweig, Holger ^{[1
]}

Kraft, Katharina ^{[1
]}

Oestreicher, Sebastian ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 35期

关键词：

boron; borylene complexes; coordination chemistry; platinum; transition metals; TERMINAL BORYLENE COMPLEXES; BRIDGING LIGAND; BORON; COORDINATION; REACTIVITY; CHEMISTRY;

D O I：

10.1002/chem.201001368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Time for T-shaped metalloborylenes: The first anionic trinuclear metal boron complex and a neutral analogue have been prepared and fully characterized. The unusual T-shaped geome-try renders the title compounds, transition-metal-base-stabilized metalloborylenes, which became available by an unprecedented direct synthetic approach. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10635 / 10637

页数：3

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